The use of stable isotopes to identify surface water–groundwater interaction in the Kruger National Park, South Africa

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
RM Petersen, JM Nel, T Strydom, E Riddell, C Coetsee, E February
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Abstract

The role of groundwater, in general, is often overlooked in freshwater ecosystem management policies and in the management of South Africa’s flagship conservation area, the Kruger National Park (KNP). To address this gap, a generalised conceptual model of surface water–ground water (sw–gw) interactions in the southern and central regions of the KNP was developed. To do this, stable isotope ratios (d18O and d2H) of groundwater, rainfall and surface water were used to determine the extent to which the base flow of perennial, seasonal and ephemeral streams on different geologies (granite vs. basalt) is driven by rainfall or groundwater. These results show that the δ18O and δ2H ratios of perennial rivers are similar to that of groundwater, while seasonal and ephemeral rivers on basalts have values closer to rainfall. On granite substrates, however, the isotope ratios of the seasonal and ephemeral rivers have values closer to groundwater than rainfall. The larger seasonal Mbyamiti River had similar isotope ratios to that of groundwater, and the highly ephemeral Nwaswitsontso had episodic interaction with groundwater (i.e. isotopic ratios overlap occasionally). These results show that decisions necessary for the sustainable management of groundwater resources are better informed when the natural interaction, movement, and exchange between groundwater and rivers are understood. This has particular relevance for large conservation areas in southern Africa that are expected to experience more variable climates in the future with both increases in drought and rainfall intensities.
在南非克鲁格国家公园,使用稳定同位素来确定地表水与地下水的相互作用
一般来说,在淡水生态系统管理政策和南非的旗舰保护区克鲁格国家公园(KNP)的管理中,地下水的作用经常被忽视。为了解决这一差距,开发了KNP南部和中部地区地表水-地下水(sw-gw)相互作用的广义概念模型。为此,使用地下水、降雨和地表水的稳定同位素比率(d18O和d2H)来确定不同地质(花岗岩与玄武岩)上的多年生、季节性和短暂溪流的基流受降雨或地下水驱动的程度。这些结果表明,多年生河流的δ18O和δ2H值与地下水相似,而玄武岩上的季节性和短暂性河流的δ18O和δ2H值更接近于降雨。然而,在花岗岩基质上,季节性和短暂性河流的同位素比值值更接近地下水,而不是降雨。较大的季节性Mbyamiti河与地下水具有相似的同位素比值,而高度短暂的Nwaswitsontso河与地下水具有偶然性的相互作用(即同位素比值偶尔重叠)。这些结果表明,当了解地下水与河流之间的自然相互作用、运动和交换时,地下水资源可持续管理所需的决策就会更好。这对南部非洲的大型自然保护区尤其重要,预计这些地区未来的气候将更加多变,干旱和降雨强度都将增加。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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