Lukang Zheng, Jin Chen, Jianke Sun, Min Liu, Yuyu Gao, Zhifeng Guo
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引用次数: 2
Abstract
The increased global demand for lithium is rapidly depleting the lithium ore reserves. Therefore, attention has turned to the recovery of lithium from aqueous solutions, such as lithium-containing brine. Compared with other methods of lithium recovery, adsorption is energy efficient and simple to implement, increasing demand for selective lithium adsorbents. In this study, a selective lithium-ion adsorbent, H4Ti5–xLa x O12, was synthesized via the sol–gel method, followed by heat treatment and acid washing. The effects of the temperature and degree of lanthanum doping (x) on the crystalline phase, morphology, lithium-ion adsorption capacity, and lithium-ion selectivity of the ion sieve were investigated, and the optimal synthetic conditions were determined. We found that doping with La3+ cations (x = 0.01) increased the lithium-ion adsorption capacity (23.96 mg g−1 at 25 °C at pH = 12; 8.2% higher than before doping), rate, and selectivity. In addition, the ion sieve could be used over multiple adsorption–desorption cycles with only a minor reduction in the lithium-ion adsorption capacity (22.88 mg g−1). Overall, these results suggest that doping with La3+ cations stabilized the H4Ti5–xLa x O12 crystal structure, alleviated particle agglomeration, expanded the lithium-ion channels, and decreased the resistance to lithium-ion migration, thus improving adsorption performance. The findings suggest that the proposed ion sieve has practical applications in the selective recovery of lithium from aqueous solutions containing a mixture of metal ions.
期刊介绍:
The Journal of Chemical Research is a peer reviewed journal that publishes full-length review and research papers in all branches of experimental chemistry. The journal fills a niche by also publishing short papers, a format which favours particular types of work, e.g. the scope of new reagents or methodology, and the elucidation of the structure of novel compounds. Though welcome, short papers should not result in fragmentation of publication, they should describe a completed piece of work. The Journal is not intended as a vehicle for preliminary publications. The work must meet all the normal criteria for acceptance as regards scientific standards. Papers that contain extensive biological results or material relating to other areas of science may be diverted to more appropriate specialist journals. Areas of coverage include: Organic Chemistry; Inorganic Chemistry; Materials Chemistry; Crystallography; Computational Chemistry.