Pengaruh Penggantian Kation-A/Sr oleh Ba pada Morfologi Partikel BaxSr(1-x)TiO3 (x = 0; 0,2; 0,4; 0,6; 0,8) Hasil Sintesis dengan Metode Lelehan Garam

Alchemy: Jurnal Penelitian Kimia Pub Date : 2021-09-09 DOI:10.20961/alchemy.17.2.48554.211-218

Hasal Maulidianingtiyas, A. Prasetiyo, Fikri Haikal, Indra Nur Cahyo, Vina Nurul Istighfarini, Anto Prasetyo

{"title":"Pengaruh Penggantian Kation-A/Sr oleh Ba pada Morfologi Partikel BaxSr(1-x)TiO3 (x = 0; 0,2; 0,4; 0,6; 0,8) Hasil Sintesis dengan Metode Lelehan Garam","authors":"Hasal Maulidianingtiyas, A. Prasetiyo, Fikri Haikal, Indra Nur Cahyo, Vina Nurul Istighfarini, Anto Prasetyo","doi":"10.20961/alchemy.17.2.48554.211-218","DOIUrl":null,"url":null,"abstract":"<div><span id=\"docs-internal-guid-460a2724-7fff-20a8-5ee3-cab002df95e2\" style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: normal; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\">SrTiO<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: normal; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\">3<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: normal; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\"> adalah material berstruktur perovskit yang dilaporkan berpotensi sebagai material fotokatalis. Penggantian pada sebagian kation-<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: italic; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\">A<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: normal; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\"> material fotokatalis berstruktur perovskit dilaporkan dapat menurunkan energi celah pitanya, akan tetapi unsur pengganti juga dilaporkan mempengaruhi morfologi partikel yang terbentuk. Dalam penelitian ini, dikaji pengaruh penggantian kation-<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: italic; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\">A<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: normal; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\"> pada SrTiO<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: normal; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\">3<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: normal; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\">(Ba<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: italic; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\">x<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: normal; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\">Sr<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: normal; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\">(1-<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: italic; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\">x<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: normal; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\">)<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: normal; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\">TiO<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: normal; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\">3<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: normal; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\"> (<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: italic; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\">x <span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: normal; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\">= 0; 0,2; 0,4; 0,6; 0,8)) terhadap morfologi partikelnya. Senyawa uji disintesis dengan metode lelehan garam dan dalam penelitian ini menggunakan garam NaCl. Difraktogram sampel menunjukkan bahwa senyawa uji berhasil disintesis kecuali pada <span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: italic; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\">x<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: normal; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\"> = 0,8 masih ditemukan senyawa pengotor yang berupa TiO<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: normal; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\">2<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: normal; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\"> dan BaCO<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: normal; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\">3<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: normal; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\">. Gambar SEM menunjukkan bahwa keberadaan kation Ba mengubah morfologi partikel dari <span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: italic; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\">nearly cubic<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: normal; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\"> menjadi bentuk polihedra dan menyebabkan<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: 400; font-style: normal; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\">ukuran partikel menjadi lebih besar.</div><div><p id=\"docs-internal-guid-0488c78a-7fff-568a-5430-127fc7bc6541\" style=\"line-height: 1.2; margin-left: 0.35pt; margin-right: -0.1pt; text-align: justify; margin-top: 6pt; margin-bottom: 6pt;\" dir=\"ltr\"><span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-weight: bold; font-style: normal; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\"> <span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-style: normal; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\">The Effect of Cation-<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-style: italic; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\">A<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; font-style: normal; font-variant: normal; text-decoration: none; vertical-align: baseline; white-space: pre-wrap;\">/Sr Replacement by Ba on Particle Morphology of Ba<span style=\"font-size: 8.5pt; font-family: 'Times New Roman'; color: #000000; background-color: transparent; fo","PeriodicalId":7926,"journal":{"name":"Alchemy: Jurnal Penelitian Kimia","volume":"39 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2021-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Alchemy: Jurnal Penelitian Kimia","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.20961/alchemy.17.2.48554.211-218","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 1

Abstract

SrTiO3 adalah material berstruktur perovskit yang dilaporkan berpotensi sebagai material fotokatalis. Penggantian pada sebagian kation-A material fotokatalis berstruktur perovskit dilaporkan dapat menurunkan energi celah pitanya, akan tetapi unsur pengganti juga dilaporkan mempengaruhi morfologi partikel yang terbentuk. Dalam penelitian ini, dikaji pengaruh penggantian kation-A pada SrTiO3(BaxSr(1-x)TiO3 (x = 0; 0,2; 0,4; 0,6; 0,8)) terhadap morfologi partikelnya. Senyawa uji disintesis dengan metode lelehan garam dan dalam penelitian ini menggunakan garam NaCl. Difraktogram sampel menunjukkan bahwa senyawa uji berhasil disintesis kecuali pada x = 0,8 masih ditemukan senyawa pengotor yang berupa TiO2 dan BaCO3. Gambar SEM menunjukkan bahwa keberadaan kation Ba mengubah morfologi partikel dari nearly cubic menjadi bentuk polihedra dan menyebabkanukuran partikel menjadi lebih besar.

The Effect of Cation-A/Sr Replacement by Ba on Particle Morphology of Ba

查看原文本刊更多论文

SrTiO3是一种具有弹性结构的物质，据报道可能是一种光合材料。据报道，在kationa -光合材料上的部分置换可以降低它们的裂隙能量，但替代物质也会影响形成的粒子形态。在本研究中，将kationa替代SrTiO3(BaxSr(1-x)TiO3 (x = 0;0.2;0.4;0.6;粒子形态学。用盐分流法合成的化合物，在这项研究中使用NaCl盐。Difraktogram的样本表明，除了x = 8上的其他化合物外，测试器已经成功地合成了它。闪的图像显示，百日咳的存在将微小的cubic形状的粒子形态转化为聚合体，使粒子的大小变得更大。巴
本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Alchemy: Jurnal Penelitian Kimia

自引率
0.00%

发文量
0

相关文献

×
引用

GB/T 7714-2015

复制

MLA

复制

APA

复制

导出至
BibTeX EndNote RefMan NoteFirst NoteExpress

×
求助内容：

期刊论文学位论文图书其他 (专利、报告等) 只需要正文仅需补充材料

应助结果提醒方式：

微信（请自行确认已关注Book学术公众号）

邮件保存

确认发布求助

×

处理提示

您的部分求助已有人上传文件，您还尚未处理，请先处理完毕再发起新的求助
点击查看

×

努力提交中

提交成功

继续求助查看详情

×
提示

您的信息不完整，为了账户安全，请先补充。
现在去补充

×

没积分了

多种获得积分方式，供你选择！
查看如何获取积分

×
提示

您因"违规操作"
具体请查看互助需知
我知道了

×
提示

现在去查看取消

×
提示

确定

×

快捷登录

密码登录

用户名：

密码：

验证码：

两周内记住我忘记密码？

手机号：

验证码：

没有帐号？现在注册

请完成安全验证×

微信好友朋友圈 QQ好友复制链接
取消

已复制链接

快去分享给好友吧!
我知道了

点击右上角分享

0