Synthesis of Some Bridged Unsymmetrical Terphthaloyl Oxime Esters

R. Bawa, Hana Mansoure Elmajdoub
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Abstract

Three unsymmetrical bridged terphthaloyl acetophenone oxime esters have been synthesized throughout an esterification process between three acetophenone oximes and the terphthaloyl chloride under mild basic conditions. Spectroscopic techniques, such as IR, HNMR and mass spectrometer, were used to confirm the structures of the desired oxime esters. The yields of the resulting oxime esters ranged from 50% to 73%.
一些桥接不对称邻苯二甲酰肟酯的合成
在温和的碱性条件下,通过三种苯乙酮肟与二苯甲酰氯的酯化反应,合成了三种不对称桥接的二苯甲酰苯乙酮肟酯。利用红外光谱、核磁共振光谱和质谱等光谱技术确定了所需要的肟酯的结构。所得肟酯的产率为50% ~ 73%。
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