Fabrication of Ag Nanorods-Embedded P3HT/PCBM Films for the Enhancement of Light Absorption

ECS Solid State Letters Pub Date : 2015-01-01 DOI:10.1149/2.0021504SSL

J. Park, Tae-Sung Bae, J. Sohn, S. Cha, Jouhahn Lee, Seong Kyu Kim, Woong-Ki Hong

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引用次数: 2

Abstract

We report a facile method for preparing hybrid nanostructured films composed of poly(3-hexlythiophene) (P3HT) and [6,6]-phenylC61-butyric acid methyl ester (PCBM) with silver (Ag) nanorods (AgNRs) array. The AgNRs were synthesized by an electrochemical deposition method using an anodic aluminum oxide template with 50-nm-pore-diameter and 10-μm-thickness. The nanostructured P3HT/PCBM film was formed by the intercalation of AgNRs into the P3HT/PCBM film. The nanostructured P3HT/PCBM film with AgNRs showed enhanced optical absorption in the spectral range of 300–650 nm due to localized surface plasmon resonance and scattering effects around the AgNRs compared with spin-coated and nanopatterned P3HT/PCBM films without AgNRs. © The Author(s) 2015. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial No Derivatives 4.0 License (CC BY-NC-ND, http://creativecommons.org/licenses/by-nc-nd/4.0/), which permits non-commercial reuse, distribution, and reproduction in any medium, provided the original work is not changed in any way and is properly cited. For permission for commercial reuse, please email: oa@electrochem.org. [DOI: 10.1149/2.0021504ssl] All rights reserved.

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银纳米棒嵌入P3HT/PCBM薄膜增强光吸收的制备

本文报道了一种用银纳米棒(AgNRs)阵列制备由聚(3-己基噻吩)(P3HT)和[6,6]-苯基c61 -丁酸甲酯(PCBM)组成的杂化纳米结构薄膜的简便方法。采用电化学沉积法制备了孔径为50 nm、厚度为10 μm的阳极氧化铝模板。将agnr嵌入到P3HT/PCBM薄膜中，形成纳米结构的P3HT/PCBM薄膜。与不含AgNRs的自旋涂覆和纳米化P3HT/PCBM薄膜相比，含AgNRs的纳米结构P3HT/PCBM薄膜由于AgNRs周围的局部表面等离子体共振和散射效应，在300-650 nm光谱范围内的光吸收增强。©作者2015。由ECS出版。这是一篇在知识共享署名非商业禁止衍生品4.0许可(CC BY-NC-ND, http://creativecommons.org/licenses/by-nc-nd/4.0/)条款下发布的开放获取文章，该许可允许在任何媒介上进行非商业重用、分发和复制，前提是原始作品不以任何方式改变并适当引用。如需商业使用许可，请发邮件至oa@electrochem.org。[DOI: 10.1149/2.0021504ssl]版权所有。

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ECS Solid State Letters MATERIALS SCIENCE, MULTIDISCIPLINARY-PHYSICS, APPLIED

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