Volume fraction and temperature dependence of mechanical properties of silicone rubber particulate/epoxy blends

Minoru Miwa, Akiyoshi Takeno, Katsumi Hara, Akira Watanabe
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引用次数: 31

Abstract

At all temperatures, both the Young's modulus and tensile strength of silicone rubber particle/epoxy resin blends decreased as the volume fraction of the silicone rubber particles was increased, and this decrease became greater with falling temperature. A volume fraction-temperature superposition held for both the Young's modulus and tensile strength of the blends. The shifted volume fraction of silicone rubber particles needed to obtain master curves increased with increasing temperature and the shift was almost the same for both properties. An optimum suitable volume fraction of rubber particles existed in terms of improving impact fracture energy. A volume fraction of silicone rubber particles of 5–10% appears to be the most suitable for obtaining a blend in which the decrease in Young's modulus and the tensile strength is relatively low and the increase in impact fracture energy is relatively high.

硅橡胶颗粒/环氧树脂共混物力学性能的体积分数和温度依赖性
在所有温度下,硅橡胶颗粒/环氧树脂共混物的杨氏模量和抗拉强度均随硅橡胶颗粒体积分数的增加而降低,且随温度的降低幅度更大。共混物的杨氏模量和抗拉强度的体积分数-温度叠加。获得主曲线所需的硅橡胶颗粒体积位移分数随温度的升高而增加,两种性能的位移几乎相同。在提高冲击断裂能方面,存在一个最佳的橡胶颗粒体积分数。硅橡胶颗粒的体积分数为5-10%似乎最适合获得杨氏模量和拉伸强度下降相对较低而冲击断裂能增加相对较高的共混物。
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