Easy to make highly efficient FG@ACC stable platform for sp3C-CF3 bond generation and NADH regeneration under sun light

IF 1.3 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY
Surendra Kumar Jaiswal, R. Yadav, Krishna Kumar, Satyam Singh, Surabhi Chaubey, Pooja S. Singh, S. Tripathi, S. K. Gupta, T. W. Kim, A. Singh
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引用次数: 0

Abstract

The conversion of sun light energy into sustainble greener chemicals are a major obstacle due to the use of expensive and toxic materials. Sun light induced trifluoromethylation emerges as a highly efficient procedure to insert trifluoromethyl groups into the organic compounds. Yet, the expensive and toxic properties of the metal-based photocatalysts creates a major obstacle for the insertion of trifluoromethyl groups. Metal free activated carbon cloth (ACC) emerged as a highly efficient pillar in the area of material science. In this work, we have successfully synthesized self-assembled metal free fast green with activated carbon cloth (FG@ACC) photocatalyst for photocatalytic trifluoromethylation and reduced nicotinamide adenine dinucleotide (NADH) cofactor regeneration (85.89 %, 2 h) under sun light. The sun light induced organic transformation promotes the use of low-cost CF3SO2Na as the CF3 radical source to produce highly selective products with 97% yield.
易于制作高效FG@ACC稳定的sp3C-CF3键生成和NADH在阳光下再生的平台
由于使用昂贵和有毒的材料,将太阳光能转化为可持续的绿色化学品是一个主要障碍。太阳光诱导的三氟甲基化是一种将三氟甲基插入有机化合物的高效方法。然而,金属基光催化剂的昂贵和毒性为三氟甲基的插入造成了主要障碍。无金属活性炭布(ACC)是材料科学领域的一个高效支柱。在这项工作中,我们成功地合成了自组装的无金属快绿活性炭布(FG@ACC)光催化剂,用于光催化三氟甲基化和还原性烟酰胺腺嘌呤二核苷酸(NADH)辅助因子在阳光下再生(85.89%,2 h)。太阳光诱导的有机转化促进了使用低成本的CF3SO2Na作为CF3自由基源,以97%的收率生产高选择性产品。
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来源期刊
Main Group Chemistry
Main Group Chemistry 化学-化学综合
CiteScore
2.00
自引率
26.70%
发文量
65
审稿时长
>12 weeks
期刊介绍: Main Group Chemistry is intended to be a primary resource for all chemistry, engineering, biological, and materials researchers in both academia and in industry with an interest in the elements from the groups 1, 2, 12–18, lanthanides and actinides. The journal is committed to maintaining a high standard for its publications. This will be ensured by a rigorous peer-review process with most articles being reviewed by at least one editorial board member. Additionally, all manuscripts will be proofread and corrected by a dedicated copy editor located at the University of Kentucky.
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