Preparation and Crystal Structure Determination of Zinc (II) Bromide Complexes at the Presence of Various Ligands

IF 3.5 Q2 CHEMISTRY, MULTIDISCIPLINARY
A. D. Khalaji, E. Shahsavani, M. Dušek, M. Kučeráková, W. Hornfeck
{"title":"Preparation and Crystal Structure Determination of Zinc (II) Bromide Complexes at the Presence of Various Ligands","authors":"A. D. Khalaji, E. Shahsavani, M. Dušek, M. Kučeráková, W. Hornfeck","doi":"10.33945/SAMI/CHEMM.2019.5.2","DOIUrl":null,"url":null,"abstract":"In this paper, we report the syntheses and crystal structuredetermination of three mononuclear and four-coordinated zinc(II) bromide complexes with chemical formula of [Zn(tsc)2]Br2 (1), Zn(PPh3)2Br2 (2) and Zn(Brcatsc)Br2 (3). The synthesized complexes are characterized by elemental analysis (CHN) and theircrystal structures are investigated by single crystal X-ray diffraction. In complex 1, the TSC coordinates to the zinc(II) ion as a bidentate ligand via N and S atoms. In complex 3, the thiosemicarbazone ligand Brcatsc coordinates to zinc(II) ion as a monodentate ligand via S atom. In these complexes, the zinc(II) ion coordinated in a distorted tetrahedral coordination geometry.","PeriodicalId":9896,"journal":{"name":"Chemical Methodologies","volume":null,"pages":null},"PeriodicalIF":3.5000,"publicationDate":"2019-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Methodologies","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.33945/SAMI/CHEMM.2019.5.2","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

Abstract

In this paper, we report the syntheses and crystal structuredetermination of three mononuclear and four-coordinated zinc(II) bromide complexes with chemical formula of [Zn(tsc)2]Br2 (1), Zn(PPh3)2Br2 (2) and Zn(Brcatsc)Br2 (3). The synthesized complexes are characterized by elemental analysis (CHN) and theircrystal structures are investigated by single crystal X-ray diffraction. In complex 1, the TSC coordinates to the zinc(II) ion as a bidentate ligand via N and S atoms. In complex 3, the thiosemicarbazone ligand Brcatsc coordinates to zinc(II) ion as a monodentate ligand via S atom. In these complexes, the zinc(II) ion coordinated in a distorted tetrahedral coordination geometry.
不同配体下锌(II)溴化配合物的制备及晶体结构测定
本文报道了化学式为[Zn(tsc)2]Br2(1)、Zn(PPh3)2Br2(2)和Zn(Brcatsc)Br2(3)的三种单核四配位溴化锌配合物的合成和晶体结构的测定。用元素分析(CHN)对合成的配合物进行了表征,并用单晶x射线衍射对其晶体结构进行了研究。在配合物1中,TSC通过N和S原子与锌离子作为双齿配体进行配位。在配合物3中,硫代氨基脲配体Brcatsc作为单齿配体通过S原子与锌(II)离子配位。在这些配合物中,锌(II)离子以扭曲的四面体配位几何配位。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Chemical Methodologies
Chemical Methodologies CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
3.10
自引率
1.80%
发文量
8
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信