Nikita Reinhardt, Jonas M. Breitsameter, Klaus Drechsler, Bernhard Rieger
{"title":"Fully Bio-Based Epoxy Thermoset Based on Epoxidized Linseed Oil and Tannic Acid","authors":"Nikita Reinhardt, Jonas M. Breitsameter, Klaus Drechsler, Bernhard Rieger","doi":"10.1002/mame.202200455","DOIUrl":null,"url":null,"abstract":"<p>Increasing demand for bio-based epoxy thermoset alternatives has risen in the last few years. Epoxidized vegetable oils (EVO) have attracted significant attention due to their bio-based, unharmful nature and high availability. This study proposes a fully bio-based epoxy thermoset based on epoxidized linseed oil (ELO) and tannic acid (TA). TA allows, with its high degree of functionality and aromatic structure as a curing agent for ELO, to create a fully bio-based polymer network with a high glass transition temperature (<i>T</i><sub>g</sub>), high stiffness, and high strength. A maximum <i>T</i><sub>g</sub> of 146 °C, a flexural modulus of 2986 MPa, and flexural strength of 72 MPa are obtained. The strong material properties of the TA/ELO thermoset expose its potential as a bio-based substitute for petrochemical-based epoxy resins for high-performance applications.</p>","PeriodicalId":18151,"journal":{"name":"Macromolecular Materials and Engineering","volume":null,"pages":null},"PeriodicalIF":4.2000,"publicationDate":"2022-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/mame.202200455","citationCount":"6","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Macromolecular Materials and Engineering","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/mame.202200455","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 6
Abstract
Increasing demand for bio-based epoxy thermoset alternatives has risen in the last few years. Epoxidized vegetable oils (EVO) have attracted significant attention due to their bio-based, unharmful nature and high availability. This study proposes a fully bio-based epoxy thermoset based on epoxidized linseed oil (ELO) and tannic acid (TA). TA allows, with its high degree of functionality and aromatic structure as a curing agent for ELO, to create a fully bio-based polymer network with a high glass transition temperature (Tg), high stiffness, and high strength. A maximum Tg of 146 °C, a flexural modulus of 2986 MPa, and flexural strength of 72 MPa are obtained. The strong material properties of the TA/ELO thermoset expose its potential as a bio-based substitute for petrochemical-based epoxy resins for high-performance applications.
期刊介绍：
Macromolecular Materials and Engineering is the high-quality polymer science journal dedicated to the design, modification, characterization, and processing of advanced polymeric materials.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
