FOTODEGRADASI ZAT WARNA METHYLENE BLUE DENGAN SINAR UV DAN FOTOKATALIS NANOPARTIKEL PERAK

I. Suprihatin, R. Suat, I. S. Negara
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Abstract

The textile industry is one of the producers of liquid waste that contains many synthetic dyes and difficult to decompose such as methylene blue (MB). Approximately 15-20% of the MB products that cannot be reused will go into the wastewater which eventually be drained into the catchment waters. This causes a variety of negative impacts, especially in the water environment. One way to prevent this problem is by decomposing the dye using UV light and accelerating the decomposition process with the photocatalysts, namely silver nanoparticles. The purpose of this study is to determine the optimal conditions for the photodegradation process of MB dyes, and the effectiveness of the degradation of MB dye under optimal conditions. The search was conducted by firstly finding the optimal conditions of the photocatalyst / NPAg volume, irradiation time, and pH. The optimal condition was then applied to photodegrade various concentrations of MB to determine the effectiveness of the process. The results showed the optimal condition of MB photodegradation was 10 mL of photocatalyst / NPAg, 60 minute irradiation time at pH 4. Under such condition, the method effectively degraded 98.21% of100 ppm MB. The method used is also effective for MB up to 150 ppm because it is able to degrade almost 100%. Keywords: photocatalyst, photodegradation, NPAg, methylene blue, plumeria rubra.
带有紫外线和银纳米催化剂的蓝色甲基色素的上相降解
纺织工业是含亚甲基蓝(MB)等合成染料难分解的废液的产生者之一。大约15-20%不能再利用的MB产品将进入废水,最终排入集水区。这就造成了各种各样的负面影响,尤其是对水环境的影响。防止这个问题的一种方法是使用紫外线分解染料,并使用光催化剂(即纳米银)加速分解过程。本研究的目的是确定MB染料光降解过程的最佳条件,以及在最佳条件下对MB染料的降解效果。首先寻找光催化剂/ NPAg体积、照射时间和ph的最佳条件,然后将最佳条件应用于光降解不同浓度的MB,以确定该工艺的有效性。结果表明:光催化剂/ NPAg用量为10 mL, pH为4,照射时间为60 min,对MB的光降解效果最佳。在此条件下,该方法对100 ppm的甲基溴的有效降解率为98.21%。该方法对高达150 ppm的甲基溴也有效,因为它能够降解几乎100%。关键词:光催化剂,光降解,NPAg,亚甲基蓝,鸡蛋花
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