CO2 and H2S Absorption in Tofu Liquid Waste Biogas using Packed Bed Scrubber with Variation of MEA Concentration and Flow Rate

Aan Ade Putra, Leila Kalsum, Abu Hasan
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Abstract

Biogas technology has become an alternative fuel that is often used in Indonesia. One of the raw materials for biogas that has the potential and is easy to obtain is waste from the tofu industry. Liquid waste still contains a lot of organic elements. The organic materials contained in the exhaust of the tofu industry are generally very high. The gases commonly found in tofu waste are nitrogen gas (N2), oxygen (O2), hydrogen sulfide (H2S), ammonia (NH3), carbon dioxide (CO2) and methane (CH4). These gases come from the decomposition of organic materials contained in wastewater. So that biogas produced from tofu liquid waste still contains CO2 and H2S gases which are quite high. Therefore, in this study the process of purification or refining of biogas products will be carried out using the absorption method through an absorber column using monoethanolamine (MEA) solution as a chemical absorbent through a 8 mm packed bed scrubber. The results showed that the best biogas flow rate in the purification process which produced the highest CH4 concentration of 95.12% was 40% MEA concentration and 0.8 L/min flow rate. The effect of MEA concentration on biogas purification causes the concentration of CO2 and H2S in the purified biogas to decrease as the MEA concentration increases. The best combination of 0.8 L/min biogas flow rate and 10 mm packing area reduces CO2 and H2S concentrations to 1.88% and 0 ppm.
填料床洗涤器对豆腐液废沼气中CO2和H2S的吸收随MEA浓度和流量的变化
沼气技术已经成为印度尼西亚经常使用的替代燃料。豆腐工业的废弃物是一种有潜力且容易获得的沼气原料。废液中仍含有大量的有机元素。豆腐工业废气中所含的有机物含量普遍很高。豆腐渣中常见的气体有氮气(N2)、氧气(O2)、硫化氢(H2S)、氨(NH3)、二氧化碳(CO2)和甲烷(CH4)。这些气体来自废水中有机物质的分解。因此,从豆腐废液中产生的沼气仍然含有相当高的二氧化碳和硫化氢气体。因此,在本研究中,沼气产品的纯化或精炼过程将采用吸附法,通过吸收塔,以单乙醇胺(MEA)溶液作为化学吸收剂,通过8mm填充床洗涤器进行。结果表明,在净化过程中,最佳沼气流量为40% MEA浓度和0.8 L/min流量,CH4浓度最高,达到95.12%。MEA浓度对沼气净化的影响导致净化后沼气中CO2和H2S的浓度随着MEA浓度的增加而降低。0.8 L/min沼气流速和10 mm填料面积的最佳组合可使CO2和H2S浓度分别降至1.88%和0 ppm。
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