Copolymerization of N-[3-dialkylaminopropyl]methacrylamides with acrylic amides and esters in organic solvents

A. Sadikov, O. Kazantsev, D. Kamorin, A. Simagin, I. R. Arifullin, D. Orekhov
{"title":"Copolymerization of N-[3-dialkylaminopropyl]methacrylamides with acrylic amides and esters in organic solvents","authors":"A. Sadikov, O. Kazantsev, D. Kamorin, A. Simagin, I. R. Arifullin, D. Orekhov","doi":"10.35164/0554-2901-2023-1-2-21-26","DOIUrl":null,"url":null,"abstract":"The radical copolymerization of N-[3-(dialkylamino)-propyl]methacrylamides with a number of (meth)acrylic amides and esters in organic solvents over a wide range of molar ratios has been studied. Co-polymerisation constants for five polymerisation systems in 1,4-dioxane and toluene have been determined by the Feinman and Ross method. The influence of the solvent on the kinetics of the copolymerization of the studied monomers was found, which manifests itself in a change of the reactivity ratios of the monomers upon varying the polarity of the medium. For the obtained polymers, the presence of thermosensitive properties in aqueous solutions and the effect of the concentration and composition of copolymers on their solubility in water were shown.","PeriodicalId":20254,"journal":{"name":"Plasticheskie massy","volume":"106 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2023-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Plasticheskie massy","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.35164/0554-2901-2023-1-2-21-26","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

Abstract

The radical copolymerization of N-[3-(dialkylamino)-propyl]methacrylamides with a number of (meth)acrylic amides and esters in organic solvents over a wide range of molar ratios has been studied. Co-polymerisation constants for five polymerisation systems in 1,4-dioxane and toluene have been determined by the Feinman and Ross method. The influence of the solvent on the kinetics of the copolymerization of the studied monomers was found, which manifests itself in a change of the reactivity ratios of the monomers upon varying the polarity of the medium. For the obtained polymers, the presence of thermosensitive properties in aqueous solutions and the effect of the concentration and composition of copolymers on their solubility in water were shown.
N-[3-二烷基氨基丙基]甲基丙烯酰胺与丙烯酸酰胺和酯类在有机溶剂中的共聚
研究了N-[3-(二烷基胺)-丙基]甲基丙烯酰胺与若干(甲基)丙烯酸酰胺和酯在有机溶剂中较宽摩尔比下的自由基共聚反应。用Feinman和Ross方法测定了五种聚合体系在1,4-二恶烷和甲苯中的共聚合常数。发现了溶剂对所研究单体共聚动力学的影响,这种影响表现为随着介质极性的改变而改变单体的反应性比。结果表明,所得共聚物在水溶液中的热敏性以及共聚物的浓度和组成对其在水中溶解度的影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信