ELECTROCHEMICAL INVESTIGATION OF PROTECTION EFFECT OF MINERAL-POLYMER COATINGS ON STEEL FOR HOUSING AND COMMUNAL SERVICES

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Abstract

The durability and protection effect of mineral-polymer coatings (MPC) on steel developed by SU-57 сompany for heat supply and housing and communal services facilities are determined. The thickness of the coatings is 150…700 μm. It is shown that MPC with a thickness of 150…500 μm in network water at 95 °C are resistant, when kept for 1…8 days, an increase in their mass is observed due to the overgrowth of MPC pores with hardness salts, corrosion products and hydroxides, which is confirmed by micrographs of the MPС surface. The outer layer of the MPC with a thickness of 700 μm is more porous and undergoes the dissolution under these conditions at an insignificant rate. According to the results of determination of the corrosion rate of steel with MPC (by the method of linear polarization resistance) in 3% NaCl at 20° and 95 °C, as well as in network water at 95 °C, coatings with a thickness of 500 and 700 μm have the highest protective ability, 82…89%, the porosity of the coatings is 11…18%. MPP on steel has ahigh adhesion. The optimal thickness of the MPP for the protection of heat supply and housing facilities according to 11…18%. MPC on steel has a high adhesion. The optimal thickness of the MPC for the protection of heat supply and housing facilities according to the results of the work is 500 μm.
矿物聚合物涂层对住宅和公共设施用钢防护效果的电化学研究
测定了矿物聚合物涂层(MPC)在SU-57公司生产的供热、住宅和公用设施用钢上的耐久性和防护效果。涂层厚度为150 ~ 700 μm。结果表明,厚度为150 ~ 500 μm的MPC在95°C的网络水中具有良好的耐蚀性,当放置1 ~ 8 d时,由于MPC孔隙中含有硬度盐、腐蚀产物和氢氧化物,其质量增加,这一点通过MPС表面的显微照片得到了证实。在这些条件下,厚度为700 μm的MPC外层多孔性更强,溶解速率不显著。用MPC(线性极化电阻法)测定钢在20°和95°C的3% NaCl和95°C的网络水中的腐蚀速率,结果表明,涂层厚度为500和700 μm时,涂层的防护能力最高,为82…89%,孔隙率为11…18%。MPP在钢上有很高的附着力。对供热和住宅设施的保护,MPP的最佳厚度为11.18%。MPC在钢上有很高的附着力。根据工作结果,保温隔热层的最佳厚度为500 μm。
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