FIELD EXPERIENCE OF DOWNHOLE EQUIPMENT OPERATION IN HYDROGEN SULFIDE-CONTAINING ENVIRONMENTS

Dmitry A. Lunin, Dmitry A. Minchenko, A. B. Noskov, I. G. Klyushin, Ilnar I. Bikaev, Dmitry I. Maltsev, Nail A. Galiev, A. Markin, V. E. Tkacheva, I. V. Valekzhanin
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Abstract

The article describes the results of operation of downhole equipment in hydrogen sulfide-containing media in relation to local and corrosion-mechanical failures. Useful life (without anti-corrosion protection) for most common manganese steel tubing before the appearance of through fracture was shown. The minimum concentrations of H2S and CO2 in the water phase for wellhead sample are shown when determining the degree of corrosivity of well media and types of corrosion depending on their concentration, in relation to carbon and low-alloy steels. The corrosion-mechanical destructions the downhole equipment were visualized according to GOST 53679. The necessity of taking into account the tendency of stainless steel grade 40Х13 (foreign analogue in the USA is AISI 420) of intersection splined couplings and shafts of an electric centrifugal pump unit made of steel grade 05Х16Н4Д2Б (foreign analogue is not defined) to hydrogen embrittlement as a result of exposure to acidic compositions (12–15 % HCl), used in technological operations, is shown. Practical solutions are proposed for tubing resistant to local and corrosion-mechanical failures (by steel grades and strength groups) based on the proposals of a domestic manufacturer. Two main factors are shown that reduce the service life of tubing and couplings to them to one year. Four polymorphic forms of iron sulfide (the main products of hydrogen sulfide (H2S-) and mixed (CO2 + H2S) corrosion), the conditions for their formation and the maximum rate of local corrosion, up to a through ulcer, under sulfide deposits, were identified. The statistics of tubing by steel grades and the percentage of their use in the fields operated by the Company are shown.
具有含硫化氢环境下井下设备操作的现场经验
本文介绍了井下设备在含硫化氢介质中局部故障和腐蚀机械故障的运行结果。显示了大多数常见锰钢管在出现贯通断裂之前的使用寿命(没有防腐保护)。在确定井介质的腐蚀程度和腐蚀类型时,井口样品水相中H2S和CO2的最低浓度显示,这取决于它们的浓度,与碳和低合金钢有关。根据GOST 53679对井下设备的腐蚀机械破坏进行了可视化。说明了考虑不锈钢级40Х13(美国的国外类似产品是AISI 420)的交叉花键联轴器和由钢级05Х16Н4Д2Б(国外类似产品未定义)制成的电动离心泵单元的轴由于暴露于工艺操作中使用的酸性成分(12 - 15% HCl)而产生氢脆的趋势的必要性。根据国内某厂家的建议,提出了抗局部和腐蚀机械失效的实用解决方案(按钢种和强度分组)。有两个主要因素导致油管及其联轴器的使用寿命缩短至一年。确定了硫化铁的四种多晶形态(硫化氢(H2S-)和混合(CO2 + H2S)腐蚀的主要产物),它们的形成条件和局部腐蚀的最大速率,在硫化物沉积物下,可达一个透性溃疡。显示了按钢种划分的油管的统计数据及其在公司经营的油田中使用的百分比。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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