L. Votavová, K. Hanušová, Lukáš Vápenka, J. Dobiáš, F. Kvasnička
{"title":"Occurrence of 2-phenylphenol in food paper packages","authors":"L. Votavová, K. Hanušová, Lukáš Vápenka, J. Dobiáš, F. Kvasnička","doi":"10.2478/s11532-014-0563-x","DOIUrl":null,"url":null,"abstract":"AbstractTwenty three paper based packaging materials commercially used for food packaging in the Czech Republic were analysed with regard to 2-phenylphenol (OPP) content using HPLC technique with fluorimetric detection. The HPLC method was modified with the aim to increase its sensitivity. OPP was detected in quantities ranging from 10 mg kg−1 to 527 mg kg−1 in twenty tested samples. The level of OPP in packaging materials was in close correlation to the content of recycled pulp in used paper material. The migration of OPP from two packaging materials comprised of paperboard coated with low density polyethylene (LDPE) into food simulants was determined at 40°C for 10 days. The levels of migration into 3% acetic acid, 10% ethanol and olive oil were below the limit of detection of used analytical procedure. In the case of 95% ethanol, 13% and 21% of OPP present in tested samples were transferred into simulant. The found occurrence of OPP in paper packages does not pose any significant safety risk for food consumer, but OPP could be considered as wide spread contaminant in paper materials.\n","PeriodicalId":9888,"journal":{"name":"Central European Journal of Chemistry","volume":"61 1","pages":"1162-1168"},"PeriodicalIF":0.0000,"publicationDate":"2014-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"9","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Central European Journal of Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2478/s11532-014-0563-x","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 9
Abstract
AbstractTwenty three paper based packaging materials commercially used for food packaging in the Czech Republic were analysed with regard to 2-phenylphenol (OPP) content using HPLC technique with fluorimetric detection. The HPLC method was modified with the aim to increase its sensitivity. OPP was detected in quantities ranging from 10 mg kg−1 to 527 mg kg−1 in twenty tested samples. The level of OPP in packaging materials was in close correlation to the content of recycled pulp in used paper material. The migration of OPP from two packaging materials comprised of paperboard coated with low density polyethylene (LDPE) into food simulants was determined at 40°C for 10 days. The levels of migration into 3% acetic acid, 10% ethanol and olive oil were below the limit of detection of used analytical procedure. In the case of 95% ethanol, 13% and 21% of OPP present in tested samples were transferred into simulant. The found occurrence of OPP in paper packages does not pose any significant safety risk for food consumer, but OPP could be considered as wide spread contaminant in paper materials.
摘要采用高效液相色谱-荧光法对捷克23种市售食品包装用纸中的2-苯基酚(OPP)含量进行了分析。对HPLC法进行了改进,以提高其灵敏度。在20个测试样品中检测到OPP的量从10 mg kg - 1到527 mg kg - 1不等。包装材料中OPP的含量与废纸中再生纸浆的含量密切相关。在40°C条件下,测定了两种包装材料(由涂有低密度聚乙烯(LDPE)的纸板组成)向食品模拟剂中的OPP迁移。对3%醋酸、10%乙醇和橄榄油的迁移量均低于常用分析方法的检出限。在95%乙醇的情况下,测试样品中存在的13%和21%的OPP被转移到模拟物中。纸包装中发现的OPP不会对食品消费者构成重大的安全风险,但OPP可以被认为是纸制品中广泛存在的污染物。