CRUSTACEAN WASTE SHELLS AS ADSORPTION MATERIALS FOR HEAVY METALS IN AN AQUEOUS SOLUTION

Queency P. Padida, Rolando V. Maningas, Christian Paul P. dela Cruz, Lustina P. Lapie, Nilda S. Alforja
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Abstract

Laguna de Bay is one of the country's major lakes, providing a third of the fish consumed by Metro Manila's 16 million residents. It also provides support for agriculture, industry, and hydropower generation, as well as providing a welcome respite for many Filipinos. However, because of the lake's importance, it is threatened by a variety of issues, including pollution. Heavy metals such as mercury and lead are present in high concentrations in the lake. And these heavy metals may persist in fish, water, air and the human body. As a result, an adsorption technique for heavy metal removal in an aqueous solution was investigated. As an adsorbent, the produced chitosan from crustacean waste shells was employed. The study's parameters were contact time, adsorbent quantity, and pH. Results showed that 0.5 g of chitosan has a higher absorption rate of 99% in 500 mg/L solutions compared to 1.0 g of chitosan with an adsorption rate of 98%. In terms of contact time, 60 minutes showed almost 100% adsorption rate while 120 minutes was 98%. With increasing pH, the amount of metal adsorption rises. This developed chitosan from crustacean waste shells indicates high capacity as adsorbent materials for heavy metals. As a result, it appears to be a viable material for water treatment.
甲壳类动物废壳对水中重金属的吸附材料
拉古纳德湾(Laguna de Bay)是菲律宾的主要湖泊之一,为大马尼拉1600万居民提供了三分之一的鱼类消费。它还为农业、工业和水力发电提供支持,并为许多菲律宾人提供了一个受欢迎的喘息机会。然而,由于湖泊的重要性,它受到各种问题的威胁,包括污染。像汞和铅这样的重金属在湖中浓度很高。这些重金属可能存在于鱼、水、空气和人体中。为此,研究了一种去除水中重金属的吸附技术。以甲壳类动物废壳为原料,制备壳聚糖作为吸附剂。研究的参数为接触时间、吸附剂用量和ph。结果表明,在500 mg/L的溶液中,0.5 g壳聚糖的吸收率为99%,1.0 g壳聚糖的吸收率为98%。在接触时间方面,60分钟的吸附率几乎为100%,120分钟的吸附率为98%。随着pH值的增加,金属吸附量增加。从甲壳类动物废壳中开发的壳聚糖具有较高的重金属吸附性能。因此,它似乎是一种可行的水处理材料。
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