Palladium-catalyzed cross-couplings in the synthesis of agrochemicals

Yuxin Zhu , Wenfeng Dong , Wenjun Tang
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引用次数: 4

Abstract

Palladium-catalyzed cross-couplings have played an increasingly important role in the synthesis of agrochemicals. In this review, the applications of palladium-catalyzed Heck reaction, Suzuki-Miyaura cross-coupling, Sonogashira coupling, Negishi cross-coupling, carbonylation, and Buchwald-Hartwig amination, in the synthesis of agrochemicals are summarized with particular emphasis on catalyst system and catalytic efficiencies. In addition, strategies and advances on ligand development in achieving high TONs for palladium-catalyzed cross-couplings applicable in agrochemical industry are discussed.

钯催化交偶联在农用化学品合成中的应用
钯催化的交叉偶联在农用化学品的合成中发挥着越来越重要的作用。本文综述了钯催化Heck反应、Suzuki-Miyaura交叉偶联、Sonogashira偶联、根岸交叉偶联、羰基化和Buchwald-Hartwig胺化在农用化学品合成中的应用,重点介绍了催化剂体系和催化效率。此外,还讨论了在农化工业中实现钯催化交偶联高吨位的配体开发策略和进展。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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CiteScore
3.50
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