Oil–Mineral Aggregate Formation on Oiled Beaches: Natural Attenuation and Sediment Relocation

Kenneth Lee , Patricia Stoffyn-Egli , Gilles H Tremblay , Edward H Owens , Gary A Sergy , Chantal C Guénette , Roger C Prince
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引用次数: 78

Abstract

The significance of oil–mineral aggregate (OMA) formation on the effectiveness of the in situ shoreline treatment options of natural attenuation (natural recovery) and sediment relocation (surf washing) was examined during field trials on two mixed-sediment (sand and pebble) beaches experimentally oiled with IF-30 oil. At both sites, the amount of oil remaining in the experimental plots was dramatically reduced within five days after sediment relocation treatments. Time-series microscopy and image analysis of breaker-zone water samples demonstrate that OMA formation occurred naturally on the oiled beaches at both sites and was accelerated by the sediment relocation procedure. Lower concentrations of OMA in the breaker zone at Site 3 are attributed to the higher wave-energy levels at this site that presumably facilitated more rapid OMA dispersion. The granulometry and mineralogy of beach sediment and of subtidal sediment trap samples indicate that the material settling in nearshore waters originated from the relocated sediment and that a portion of the finer sediment was probably transported out of the study region before settling. Gas chromatography/mass spectrometry analysis demonstrated that a significant fraction of the oil dispersed into nearshore waters and sediments by interaction with mineral fines was biodegraded. The fact that little or no residual oil was found stranded on the shore in areas adjacent to the experimental plots and that only small amounts of oil were found in nearshore subtidal sediments and sediment trap samples suggests that a large fraction of the oil lost from the experimental plots may have been dispersed in the form of relatively buoyant OMA.

含油海滩上的油气集合体形成:自然衰减和沉积物迁移
在两个混合沉积物(砂和卵石)海滩上进行了现场试验,研究了油矿骨料(OMA)形成对自然衰减(自然恢复)和沉积物迁移(海浪冲刷)等原位岸线处理方案的有效性的重要性。在这两个地点,经过沉积物迁移处理后的5天内,试验田中残留的油量显著减少。时间序列显微镜和破碎带水样的图像分析表明,在两个地点的受油海滩上,OMA的形成是自然发生的,并且泥沙迁移过程加速了OMA的形成。3号站点的破断区OMA浓度较低是由于该站点较高的波能水平,这可能促进了OMA更快的扩散。滩涂沉积物和潮下沉积物捕集器样品的粒度和矿物学分析表明,近岸水域沉积的物质来源于重新定位的沉积物,部分较细的沉积物可能在沉降前被运出研究区。气相色谱/质谱分析表明,通过与矿物颗粒相互作用,分散到近岸水域和沉积物中的大部分石油被生物降解。在实验区附近的海岸上发现很少或没有发现滞留的残余石油,在近岸潮下沉积物和沉积物捕集器样本中只发现少量石油,这一事实表明,实验区损失的大部分石油可能以相对浮力较大的OMA的形式分散。
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