Study on Low-Toxicity Fire-Retardant Treated Technology of Wood

Wenyan Tian, Yi-qiang Wu, W. Peng, Yunchu Hu
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引用次数: 1

Abstract

Wood is widely used as the materials for architecture, furniture and interor decoration. However, the conflagration is so serious that the fire retardant treatment has become urgent for wood materials. As more and more stress is laid on health and environment protection, fire retardant develops toward low toxicity and smoke suppression. In order to explore a low-toxic and highly-efficient fire retarding treatment technology, Eucalyptus.sp. and Choerospondias axillaris(Roxb.) wood were chosen as experiment materials, and a low-toxic fire-retardant solution consisting of dicyandiamide, phosphoric acid, boric acid, and triethanolamine was applied. The influence factors including concentration(A), temperature(B), pressure(C), soaking time(D) were investigated with orthogonal method, and TG and DSC evaluation were conducted. What's more, the oxygen index and smoke density were measured to seek for the best treatment technique. The results are as follows: (1) On the one hand, FRW itself contains no heavy metal, formaldehyde or any other toxic substance, therefore, it won't pollute the environment or hazard people's health when in use. On the other hand, barely smoke or toxic gas generate during the pyrolysis process of the wood treated with fire retardant. Therefore, FSW is a low-toxic fire retardant. In addition, it also has good fire retardant properties. (2) The best production condition for Eucalyptus sp. was A3B3ClD2,and the best production condition for Choerospondias axillaris (Roxb.) was A3B3C3D1.
木材低毒阻燃处理技术的研究
木材被广泛用作建筑、家具和室内装饰材料。然而,由于火灾的严重,对木材材料进行阻燃处理已成为当务之急。随着人们对健康和环境保护的重视,阻燃剂向低毒和抑烟方向发展。为了探索一种低毒高效的阻燃处理技术,桉树。实验材料选用腋窝绵(Choerospondias axillaris, Roxb.)木材,采用由双氰胺、磷酸、硼酸、三乙醇胺组成的低毒阻燃液。采用正交试验法考察了浓度(A)、温度(B)、压力(C)、浸泡时间(D)等影响因素,并进行了TG和DSC评价。并通过测定氧指数和烟密度,寻求最佳处理工艺。结果表明:(1)一方面,FRW本身不含重金属、甲醛等有毒物质,在使用过程中不会污染环境,危害人体健康。另一方面,经阻燃剂处理的木材在热解过程中几乎不产生烟雾和有毒气体。因此,FSW是一种低毒阻燃剂。此外,它还具有良好的阻燃性能。(2)桉树的最佳生产条件为A3B3ClD2,腋窝棘虫的最佳生产条件为A3B3C3D1。
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