Involvement of products of thermal processing of polymer waste into the raw material pool of oil refinery plants

M.P. Usmanov, P.P. Gimaletdinov, S. F. Valeev, F.P. Zainullov, A.B. Sulimov, M.B. Zheleznov
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Abstract

The directions of involving the products of thermal processing of polymer waste into the raw material pool of oil refineries are considered. A detailed analysis of fractions 85-180 oC, 180-360 oC and 360-KK oC, isolated from thermolysis products, has been carried out. Fractions 85-180 °C, 180-360 °C of thermolysis oil are characterized by a high content of organosulfur compounds, which necessitates their hydrotreating before use. After desulfurization, gasoline and diesel fractions can be used in the composition of gasoline and diesel fuels, respectively. The diesel fraction of 180-360 °C of thermolysis oil has a high cetane number and can be considered as a cetane-increasing component. Fraction 360-КК оС thermolysis oil is a potential component of catalytic cracking feedstock. The highest degree of conversion and the yield of valuable components (gasoline, propylene, butane-butene fraction) are achieved during cracking of feedstock containing 30 wt. % of the heavy part of thermolysis oil.
聚合物废弃物热加工后的产物进入炼油厂原料池
探讨了将聚合物废弃物热加工产物引入炼油厂原料池的方向。详细分析了从热解产物中分离出的85-180 oC、180-360 oC和360-KK oC馏分。85-180°C和180-360°C的热解油馏分的特点是有机硫化合物含量高,使用前需要加氢处理。脱硫后的汽油馏分和柴油馏分可分别作为汽油和柴油燃料的组成部分。180 ~ 360℃裂解油的柴油馏分十六烷值较高,可认为是增十六烷组分。馏分360-КК оС热裂解油是催化裂化原料的潜在组分。当原料中含有30 wt. %的热裂解油重质部分时,转化率和有价组分(汽油、丙烯、丁烷-丁烯馏分)的收率最高。
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