{"title":"Correlation between network structure and brittleness of triallyl isocyanurate resins as compared with diallyl phthalate resins","authors":"Akira Matsumoto, Tsuyoshi Kubo, Toru Yamakawa, Hiroyuki Aota, Yoshihiro Takayama, Akinori Kameyama, Tsuneo Nakanishi","doi":"10.1002/(SICI)1522-9505(19990701)268:1<36::AID-APMC36>3.0.CO;2-0","DOIUrl":null,"url":null,"abstract":"<p>It is not possible to improve the toughness of triallyl isocyanurate (TAIC) resins by applying the procedures useful for diallyl phthalate (DAP) resins as typical allyl resins. The results obtained are discussed in connection with the network structure of TAIC resin. Thus, the polymerization of TAIC would provide a homogeneous network accompanied by the incomplete occurrence of intermolecular crosslinking reactions caused by the rigidity of polymer chains, although DAP resins would consist of the microheterogeneous networks as the agglomerate of colloidal particles.</p><p>Es war nicht möglich, die Zähigkeit von Triallylisocyanurat (TAIC)-Harzen mit den Methoden zu verbessern, die bei Diallylphthalat (DAP)-Harzen als typischen Allylharzen zum Erfolg führen. Die erhaltenen Ergebnisse werden im Zusammenhang mit der Netzwerkstruktur der TAIC-Harze diskutiert. Demnach sollte die Polymerisation von TAIC zu einem homogenen Netzwerk führen, begleitet von unvollständigen intermolekularen Vernetzungsreaktionen aufgrund der Polymerkettensteifigkeit, wogegen DAP-Harze aus mikroheterogenen Netzwerken als Agglomerat kolloidaler Teilchen bestehen.</p>","PeriodicalId":18151,"journal":{"name":"Macromolecular Materials and Engineering","volume":null,"pages":null},"PeriodicalIF":4.2000,"publicationDate":"1999-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Macromolecular Materials and Engineering","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/%28SICI%291522-9505%2819990701%29268%3A1%3C36%3A%3AAID-APMC36%3E3.0.CO%3B2-0","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 1
Abstract
It is not possible to improve the toughness of triallyl isocyanurate (TAIC) resins by applying the procedures useful for diallyl phthalate (DAP) resins as typical allyl resins. The results obtained are discussed in connection with the network structure of TAIC resin. Thus, the polymerization of TAIC would provide a homogeneous network accompanied by the incomplete occurrence of intermolecular crosslinking reactions caused by the rigidity of polymer chains, although DAP resins would consist of the microheterogeneous networks as the agglomerate of colloidal particles.
Es war nicht möglich, die Zähigkeit von Triallylisocyanurat (TAIC)-Harzen mit den Methoden zu verbessern, die bei Diallylphthalat (DAP)-Harzen als typischen Allylharzen zum Erfolg führen. Die erhaltenen Ergebnisse werden im Zusammenhang mit der Netzwerkstruktur der TAIC-Harze diskutiert. Demnach sollte die Polymerisation von TAIC zu einem homogenen Netzwerk führen, begleitet von unvollständigen intermolekularen Vernetzungsreaktionen aufgrund der Polymerkettensteifigkeit, wogegen DAP-Harze aus mikroheterogenen Netzwerken als Agglomerat kolloidaler Teilchen bestehen.
期刊介绍：
Macromolecular Materials and Engineering is the high-quality polymer science journal dedicated to the design, modification, characterization, and processing of advanced polymeric materials.
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