Mild construction of N-fused polycyclic compounds via Rh(III)/EosinY co-catalyze C−H activation

Zhouping Wu , Guanghui Lv , Zheng Lin , Jiangyan Tang , Jian Chen , Jianghong Liu , Li Hai , Yong Wu
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引用次数: 0

Abstract

The construction of N-fused polycyclic compounds at room temperature via the combination of transition-metal catalyst and photocatalyst has been reported. This novel work has successfully realized LED irradiated C−H activation of iodonium ylides. The strategy shows wide substrate scope and ideal functional group tolerance. Our work would be useful for the construction of various heterocyclic compounds.

Abstract Image

Abstract Image

通过Rh(III)/EosinY共同催化C-H活化温和构建N-融合多环化合物
有报告称,通过过渡金属催化剂和光催化剂的结合,可在室温下构建 N-融合多环化合物。这项新工作成功实现了 LED 照射下碘化铵酰化物的 C-H 活化。该策略具有广泛的底物范围和理想的官能团耐受性。我们的工作将有助于构建各种杂环化合物。
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CiteScore
14.40
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