Constructing superior rate-performance manganese-based anode for lithium-ion batteries by tuning interface effect

IF 1.7 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
Shenghe Wang, Song Li, Qianqian Cui, Z. Wen, Juncai Sun
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引用次数: 0

Abstract

Interface engineering is an effective way to improve the electrochemical performance of electrode materials for LIBs. Point contact interfaces in composites are constructed by growing of Mn3O4 nanoparticles on the surface of acetylene black (AB). The prepared electrode materials exhibit excellent rate capability (355.7 mAh g−1 at 6.4 A g−1) and cycling stability (1386.7 mAh g−1 after 300 cycles at 1 A g−1). The presence of AB in the composite reduces the charge transfer resistance and improves the cycling stability of the electrode. Moreover, the interface between the composites increases the contribution of pseudocapacitance, which will facilitate the electrode kinetics. The construction of interfaces in the composites provides a promising perspective for the design of high-power density anode for LIBs. Highlights Construction of Mn3O4 nanoparticles on 0 D-AB spheres was proposed and synthesised by a facile and scalable strategy. The composite materials exhibit excellent electrochemical performance. The superior rate performance is mainly attributed to the interface effect of composite material.
通过调节界面效应构建高倍率性能的锂离子电池锰基阳极
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来源期刊
Materials Science and Technology
Materials Science and Technology 工程技术-材料科学:综合
CiteScore
2.70
自引率
5.60%
发文量
0
审稿时长
3 months
期刊介绍: 《Materials Science and Technology》(MST) is an international forum for the publication of refereed contributions covering fundamental and technological aspects of materials science and engineering.
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