Shenghe Wang, Song Li, Qianqian Cui, Z. Wen, Juncai Sun
{"title":"Constructing superior rate-performance manganese-based anode for lithium-ion batteries by tuning interface effect","authors":"Shenghe Wang, Song Li, Qianqian Cui, Z. Wen, Juncai Sun","doi":"10.1080/02670836.2023.2245655","DOIUrl":null,"url":null,"abstract":"Interface engineering is an effective way to improve the electrochemical performance of electrode materials for LIBs. Point contact interfaces in composites are constructed by growing of Mn3O4 nanoparticles on the surface of acetylene black (AB). The prepared electrode materials exhibit excellent rate capability (355.7 mAh g−1 at 6.4 A g−1) and cycling stability (1386.7 mAh g−1 after 300 cycles at 1 A g−1). The presence of AB in the composite reduces the charge transfer resistance and improves the cycling stability of the electrode. Moreover, the interface between the composites increases the contribution of pseudocapacitance, which will facilitate the electrode kinetics. The construction of interfaces in the composites provides a promising perspective for the design of high-power density anode for LIBs. Highlights Construction of Mn3O4 nanoparticles on 0 D-AB spheres was proposed and synthesised by a facile and scalable strategy. The composite materials exhibit excellent electrochemical performance. The superior rate performance is mainly attributed to the interface effect of composite material.","PeriodicalId":18232,"journal":{"name":"Materials Science and Technology","volume":"43 1","pages":""},"PeriodicalIF":1.7000,"publicationDate":"2023-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Science and Technology","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1080/02670836.2023.2245655","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Interface engineering is an effective way to improve the electrochemical performance of electrode materials for LIBs. Point contact interfaces in composites are constructed by growing of Mn3O4 nanoparticles on the surface of acetylene black (AB). The prepared electrode materials exhibit excellent rate capability (355.7 mAh g−1 at 6.4 A g−1) and cycling stability (1386.7 mAh g−1 after 300 cycles at 1 A g−1). The presence of AB in the composite reduces the charge transfer resistance and improves the cycling stability of the electrode. Moreover, the interface between the composites increases the contribution of pseudocapacitance, which will facilitate the electrode kinetics. The construction of interfaces in the composites provides a promising perspective for the design of high-power density anode for LIBs. Highlights Construction of Mn3O4 nanoparticles on 0 D-AB spheres was proposed and synthesised by a facile and scalable strategy. The composite materials exhibit excellent electrochemical performance. The superior rate performance is mainly attributed to the interface effect of composite material.
期刊介绍:
《Materials Science and Technology》(MST) is an international forum for the publication of refereed contributions covering fundamental and technological aspects of materials science and engineering.