UNSYMMETRICAL DISULPHIDES AS ADDITIVES TO TRANSMISSION OILS

Abstract

This paper presents the results of studies of the anti-seize properties of (2,2-dimethyl-4-methylene1,3-dioxolane-allyl and benzyl)disulfides synthesized on the basis of 2,2-dimethyl-4-chloromethyl-1,3- dioxolane, sodium disulfide and allyl and benzyl chlorides, respectively, in the composition of transmission oils. The synthesized compounds are new compounds not previously described in the literature, the structure of which has been proven by studying their physicochemical properties, elemental composition, and IR spectroscopy. It revealed that the synthesized compounds in terms of extreme pressure efficiency are significantly superior to transmission oil MS-20, as well as bis(2,2-dimethyl-4-methyl-1,3- dioxolane)disulfide, previously synthesized by the authors of this article and a typical extreme pressure additive ethylene-bis-isopropylxanthate (LZ-23k). It found that the replacement of one of the 1,3-diocosolane fragment in bis(2,2-dimethyl-4-methylene-1,3-dioxolane) disulfide with allyl or benzyl radicals leads to an improvement in anti-seize properties due to their better adsorption on metal surfaces of rubbing parts.