Physicochemical characteristics of monodispersed chromium hydroxide particles

Ryszard Sprycha , Jerzy Jablonski , Egon Matijević
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引用次数: 8

Abstract

The mechanism of the formation and growth of spherical amorphous chromium hydroxide particles of narrow size distribution by aging chrome alum solutions at elevated temperatures is described. Since the precipitation is controlled by the presence of the sulfate ion, the reaction was followed by monitoring the change in the concentrations of this anion using the sulfur-35 radioisotope and of the chromium ion by atomic absorption.

The charges and zeta potentials of the particles, determined by potentiometric titration and electrophoretic measurements, showed that the particles behaved as rigid gels.

单分散氢氧化铬颗粒的物理化学特性
叙述了铬明矾溶液高温时效制备窄尺寸分布球形非晶态氢氧化铬颗粒的形成和生长机理。由于沉淀是由硫酸盐离子的存在控制的,因此在反应之后,使用硫-35放射性同位素监测阴离子浓度的变化,并通过原子吸收监测铬离子的浓度变化。用电位滴定法和电泳法测定了颗粒的电荷和zeta电位,结果表明颗粒表现为刚性凝胶。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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