Biju R. , Vanaja Raghavan J.R. , Ravikumar R. , Indulal C.R.
{"title":"Polypyrrole-based copper oxide-nickel oxide nanocomposites in wastewater treatment, bacterial control and agricultural usage","authors":"Biju R. , Vanaja Raghavan J.R. , Ravikumar R. , Indulal C.R.","doi":"10.1016/j.plana.2022.100016","DOIUrl":null,"url":null,"abstract":"<div><p>Polymer matrix nanocomposites are in high demand and have attracted great interest in the expansion of new functional materials owing to their potential in environmental remediation applications. In this context, Polypyrrole-Based Copper oxide-Nickel oxide Nanocomposite (PPCN) was successfully fabricated by combining chemical co-precipitation and in-situ polymerization methods. The chemical co-precipitation technique was used to synthesize Copper oxide-Nickel oxide Nanocomposite using citric acid as a capping agent and in-situ polymerization method was applied to produce Polypyrrole (PPY). The photocatalytic process is a green technology that is developing as a viable option, for removing a variety of toxic pollutants, and antibacterial activity in surface water irrigation is beneficial for the protection of the edible crops from the microbial and dye pollutants in wastewater. The synthesized PPCN is investigated for its photocatalytic properties and for antibacterial activities and is safe for the environment making them a promising material for wide-ranging applications including wastewater treatment, bacterial control, and agricultural purposes. The photocatalytic behavior of the PPCN was studied for the removal of dyes under UV irradiation and showed that these polymer-based nanocomposites could remove and destroy the dye contaminants in high worth. Moreover, the PPCN acts as an excellent catalyst and observed a remarkable dye degradation efficiency of 86% in Alizarin Red (AR) and 80% in Toluidine Blue (TB) dyes within 5hrs. The results show that the PPCN could be used as a well-performing catalyst for water contamination removal. In addition, the antibacterial results indicate that the maximum antibacterial action is against Staphylococcus aureus (S. aureus), Bacillus cereus (B. cereus), and Escherichia coli (E. coli).</p></div>","PeriodicalId":101029,"journal":{"name":"Plant Nano Biology","volume":"2 ","pages":"Article 100016"},"PeriodicalIF":0.0000,"publicationDate":"2022-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S277311112200016X/pdfft?md5=bcf7b9dee3029b9f3a7fdbee6698477c&pid=1-s2.0-S277311112200016X-main.pdf","citationCount":"2","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Plant Nano Biology","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S277311112200016X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 2
Abstract
Polymer matrix nanocomposites are in high demand and have attracted great interest in the expansion of new functional materials owing to their potential in environmental remediation applications. In this context, Polypyrrole-Based Copper oxide-Nickel oxide Nanocomposite (PPCN) was successfully fabricated by combining chemical co-precipitation and in-situ polymerization methods. The chemical co-precipitation technique was used to synthesize Copper oxide-Nickel oxide Nanocomposite using citric acid as a capping agent and in-situ polymerization method was applied to produce Polypyrrole (PPY). The photocatalytic process is a green technology that is developing as a viable option, for removing a variety of toxic pollutants, and antibacterial activity in surface water irrigation is beneficial for the protection of the edible crops from the microbial and dye pollutants in wastewater. The synthesized PPCN is investigated for its photocatalytic properties and for antibacterial activities and is safe for the environment making them a promising material for wide-ranging applications including wastewater treatment, bacterial control, and agricultural purposes. The photocatalytic behavior of the PPCN was studied for the removal of dyes under UV irradiation and showed that these polymer-based nanocomposites could remove and destroy the dye contaminants in high worth. Moreover, the PPCN acts as an excellent catalyst and observed a remarkable dye degradation efficiency of 86% in Alizarin Red (AR) and 80% in Toluidine Blue (TB) dyes within 5hrs. The results show that the PPCN could be used as a well-performing catalyst for water contamination removal. In addition, the antibacterial results indicate that the maximum antibacterial action is against Staphylococcus aureus (S. aureus), Bacillus cereus (B. cereus), and Escherichia coli (E. coli).
聚合物基纳米复合材料由于其在环境修复方面的潜在应用前景,在新型功能材料的拓展方面受到了广泛的关注。在此背景下,通过化学共沉淀法和原位聚合法制备了聚吡咯基氧化铜-氧化镍纳米复合材料(PPCN)。以柠檬酸为封盖剂,采用化学共沉淀法合成氧化铜-氧化镍纳米复合材料,并采用原位聚合法制备聚吡咯(PPY)。光催化工艺是一种绿色技术,正在发展成为去除多种有毒污染物的可行选择,地表水灌溉中的抗菌活性有利于保护食用作物免受废水中微生物和染料污染物的污染。合成的PPCN具有光催化性能和抗菌活性,对环境安全,是一种具有广泛应用前景的材料,包括废水处理、细菌控制和农业用途。研究了PPCN在紫外光照射下的光催化脱除染料的行为,表明这些聚合物基纳米复合材料能够高值地脱除和破坏染料污染物。此外,PPCN作为一种优良的催化剂,在5h内对Alizarin Red (AR)和Toluidine Blue (TB)染料的降解效率分别达到86%和80%。结果表明,PPCN可以作为一种性能良好的去除水污染的催化剂。此外,抑菌结果表明,对金黄色葡萄球菌(S. aureus)、蜡样芽孢杆菌(B. cereus)和大肠杆菌(E. coli)的抑菌作用最大。