Sensitization of track etching in CR-39 by copolymerization with methacryloyl-L-alanine methyl ester

Masao Tamada, Masaru Yoshida, Masaharu Asano, Hideki Omichi, Ryoichi Katakal, Christine Trautmann, Johann Vetter, Reimar Shohr
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引用次数: 1

Abstract

Copolymer films of diethyleneglycol-bis-allylcarbonate (monomer of CR-39) and selected volume percentages of methacryloyl-L-alanine methyl ester (MA-L-AlaOMe) between 5 and 60% were irradiated with Au ions of 13 MeV nucl-1 and etched in NaOH solution at 60°C. Sensitization of track etching was observed for NaOH concentrations of 4 and 6 N. The maximum reduced etch-rate ratio, Vt/Vb-1, was obtained for the copolymer of 90% of CR-39 monomer and 10% of MA-L-AlaOMe at 4 N NaOH, which was 3.6 times higher than that for pure CR-39. The sensitization was accompanied by an increase in Vb so that the etching time could be reduced to ca 1/30 in comparison with that for pure CR-39.

甲基丙烯酰丙氨酸甲酯共聚对CR-39中径迹蚀刻的增感作用
用13MeV核-1的Au离子照射二甘醇双烯丙基碳酸酯(CR-39单体)和选定体积百分比在5和60%之间的甲基丙烯酰基-L-丙氨酸甲酯(MA-L-AlaOMe)的共聚物膜,并在60°C的NaOH溶液中蚀刻。当NaOH浓度为4和6N时,观察到轨迹蚀刻的增敏作用。在4N的NaOH下,90%的CR-39单体和10%的MA-L-AlaOMe的共聚物获得了最大的降低蚀刻速率比Vt/Vb-1,这是纯CR-39的3.6倍。增敏伴随着Vb的增加,因此与纯CR-39相比,蚀刻时间可以减少到约1/30。
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