Ba3(BS3)(PS4): the first alkaline-earth metal thioborate–thiophosphate with strong optical anisotropy originating from planar [BS3] units†

IF 3.5 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2023-10-26 DOI:10.1039/D3DT02807K

Jiazheng Zhou, Linan Wang, Hongshan Wang, Ling Luo, Junjie Li and Feng Yu

引用次数: 0

Abstract

The first alkaline-earth metal thioborate–thiophosphate Ba₃(BS₃)(PS₄) was designed from Ba₃(BO₃)(PO₄) by S–O substitution and fabricated experimentally. The [BS₃] pseudo-layers formed in the structure contribute to the strong optical anisotropy and a large birefringence of ∼0.11 at 1064 nm. The results enrich the structural and chemical diversity of chalcogenides.

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Ba3（BS3）（PS4）：第一种由平面[BS3]单元产生的具有强光学各向异性的碱土金属硫代硼酸盐硫代磷酸盐。

以Ba3（BO3）（PO4）为原料，通过S-O取代设计并制备了第一个碱土金属硫代硼酸盐硫代磷酸盐Ba3（BS3）（PS4）。在结构中形成的[BS3]伪层有助于在1064nm处产生强大的光学各向异性和约0.11的大双折射。研究结果丰富了硫族化合物的结构和化学多样性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.