Evaluation of Oilseeds for Biodiesel Production

C. D. S. C. D. Luz, F. Mainier, L. P. C. Monteiro
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引用次数: 1

Abstract

Biofuels are less polluting alternatives because they are not fossil fuels. In Brazil, the biodiesel program aims to incorporate raw vegetable material into conventional diesel oil (2 to 5%) or even replace it entirely as a fuel for adapted diesel engines. As Brazil is one of the largest producers of soybeans in the world, soybeans are the oleaginous plant most used for biodiesel production in Brazil, even if they don’t constitute the best option in relation to the yield of oil produced. The oil content of soybeans is about 19%, while canola and sunflower feature, respectively, 38 and 42% oil. The productivity of oil (in terms of kg/ha) of both canola and sunflower also surpasses soybeans. In addition to the three already mentioned oils (canola, sunflower and soya), coconut and corn oils were studied, totaling five oils. Transesterification was used with ethanol via basic catalysis using sodium hydroxide catalyst. The reaction time was 30 minutes, with the original oils heated to 50C; however, the reactions were carried out at room temperature. The synthesis with coconut oil had the lowest yield; the others (canola, sunflower, maize and soya) achieved yields on the order of 70%.
生物柴油生产油籽的评价
生物燃料是污染较少的替代品,因为它们不是化石燃料。在巴西,生物柴油计划的目标是将植物原料加入传统柴油(2%至5%),甚至完全取代它作为改装柴油发动机的燃料。由于巴西是世界上最大的大豆生产国之一,大豆是巴西生产生物柴油最常用的含油植物,即使它们不是生产石油的最佳选择。大豆含油量约为19%,菜籽油和向日葵含油量分别为38%和42%。油菜籽和向日葵的产量(以公斤/公顷计)也超过大豆。除了已经提到的三种油(菜籽油、葵花籽油和大豆油)外,还研究了椰子油和玉米油,共计五种油。以氢氧化钠为催化剂,碱催化乙醇进行酯交换反应。反应时间为30分钟,原油加热至50℃;然而,这些反应是在室温下进行的。以椰子油为原料合成收率最低;其他作物(油菜籽、向日葵、玉米和大豆)的产量达到70%左右。
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