In Situ Construction of a Coordination Zirconocene Tetrahedron

IF 4.7 2区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Inorganic Chemistry Pub Date : 2013-11-26 DOI:10.1021/ic402428m

Guoliang Liu, Zhanfeng Ju, Daqiang Yuan*, Maochun Hong

引用次数: 93

Abstract

The current study describes the first in situ synthesis and characterization of a new family of cationic coordination tetrahedra of both the V₄F₄ and V₄E₆ type, which are constructed by a new building block based on a trinuclear zirconocene moiety and the dicarboxylate or tricarboxylate anions.

Abstract Image

查看原文本刊更多论文

配位锆新世四面体的原位构造

本研究首次在原位合成和表征了一个新的V4F4和V4E6型阳离子配位四面体家族，它是由基于三核锆新世片段和二羧酸盐或三羧酸盐阴离子的新构建块构建的。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Inorganic Chemistry 化学-无机化学与核化学

CiteScore

7.60

自引率

13.00%

发文量

1960

审稿时长

1.9 months

期刊介绍： Inorganic Chemistry publishes fundamental studies in all phases of inorganic chemistry. Coverage includes experimental and theoretical reports on quantitative studies of structure and thermodynamics, kinetics, mechanisms of inorganic reactions, bioinorganic chemistry, and relevant aspects of organometallic chemistry, solid-state phenomena, and chemical bonding theory. Emphasis is placed on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding properties of significant new and known compounds.