A Research of the Material of the Core of Metal Threads from the Fourteenth-Century Slabbed Graves at the Plateau of Eski-Kermen

Nicolas Produit, A. Kamaev, A. Loboda, E. Tereschenko, E. Khairedinova, Ekaterina B. Yatsishina
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Abstract

In 2020, the excavations of the fourteenth-century burials in slabbed graves 5/2020 and 8/2020 located in front of the main basilica in the central area of the town atop of the plateau of Eski-Kermen discovered metal threads of thin strips of precious metal spirally wound round the core. The present research analyses the material of this core. It is known that most often the strips of precious metal were wound around the core with protein base (silk, wool, or hair) or with cellulose base (linen, cotton, or hemp). The samples of three metal threads were analysed, though no preserved organic core was found in one of the samples. Electron microscopy of the threads recorded their fibrous core, thus showing that the base of metal threads was not hair, skin, or tendons. Further, the core material was investigated by gas chromatography – mass spectrometry. The research detected trace amounts of two amino-acids, glycine and alanine, which appeared in silk fibroin only. The results of this study suggest that the core of metal threads was made of silk cloth. This indicates an imported, probably Mediterranean origin of the metal threads found in the burials at Eski-Kermen plateau. The artefacts made of such threads were possibly brought to the Crimea by Genoese merchants. It is known that in the fourteenth century various silk cloths were a priority commodity in the trade carried on by the Italians in Caffa and the towns of Genoese Gazaria.
14世纪艾斯基-克尔曼高原板墓金属线芯材料研究
2020年,对位于埃斯基-克尔曼高原上城镇中心地区主教堂前的5/2020和8/2020号14世纪墓葬的挖掘发现了金属线,这些金属线是细长的贵金属条螺旋缠绕在核心上。本研究对该岩心的材料进行了分析。众所周知,贵金属条通常是用蛋白质基(丝绸、羊毛或头发)或纤维素基(亚麻、棉花或大麻)缠绕在核心上的。对三根金属线的样品进行了分析,但在其中一根样品中没有发现保存完好的有机芯。金属线的电子显微镜记录了它们的纤维芯,从而表明金属线的底部不是头发、皮肤或肌腱。采用气相色谱-质谱联用技术对核心材料进行了研究。该研究发现了两种微量的氨基酸,甘氨酸和丙氨酸,这两种氨基酸只出现在丝素中。该研究结果表明,金属线的核心是由丝绸制成的。这表明在埃斯基-克尔曼高原的墓葬中发现的金属线是进口的,可能来自地中海。用这种线制成的手工艺品可能是热那亚商人带到克里米亚的。众所周知,在14世纪,各种丝绸是意大利人在卡法和热那亚加扎里亚城镇进行贸易的优先商品。
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