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“On Water”: Unique Reactivity of Organic Compounds in Aqueous Suspension†

IF 16.9 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Angewandte Chemie International Edition Pub Date : 2005-05-17 DOI:10.1002/anie.200462883
Sridhar Narayan Dr., John Muldoon Dr., M. G. Finn Prof., Valery V. Fokin Prof., Hartmuth C. Kolb Prof., K. Barry Sharpless Prof.
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引用次数: 1306

Abstract

Water, the medium of choice: Many reactions, such as Claisen rearrangements (see scheme), are dramatically accelerated when performed in aqueous suspension (“on water”) relative to organic solvents or even neat conditions. Low miscibility of organic compounds with water is not detrimental: in fact, it facilitates the isolation of products.

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