Synthetic study on the angular triquinanes

IF 1 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Journal of The Serbian Chemical Society Pub Date : 2023-01-01 DOI:10.2298/jsc230627046s

M. Stjepanović, A. Janković, B. Vulovic, R. Matovic, R. Saicic

引用次数: 0

Abstract

The synthesis of an angular triquinane, which could serve as a suitable platform for the synthesis of several natural products (panaginsene, silphinene, senoxydene) is described. The synthesis is based on two consecutive cyclopentene annulations, where alkenes were used as latent carbonyl functionalities (via Wacker reaction), and cyclopentenone annulation was effected by aldol condensation.

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角型三醌类化合物的合成研究

本文描述了一种角状三醌的合成，它可以作为合成几种天然产物(panaginense, silphinene, senoxydene)的合适平台。该合成基于两个连续环戊烯环，其中烯烃作为潜在羰基官能团(通过瓦克反应)，环戊烯酮环是通过醛醇缩合而形成的。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of The Serbian Chemical Society 化学-化学综合

CiteScore

1.80

自引率

0.00%

发文量

审稿时长

1 months

期刊介绍： The Journal of the Serbian Chemical Society -JSCS (formerly Glasnik Hemijskog društva Beograd) publishes articles original papers that have not been published previously, from the fields of fundamental and applied chemistry: Theoretical Chemistry, Organic Chemistry, Biochemistry and Biotechnology, Food Chemistry, Technology and Engineering, Inorganic Chemistry, Polymers, Analytical Chemistry, Physical Chemistry, Spectroscopy, Electrochemistry, Thermodynamics, Chemical Engineering, Textile Engineering, Materials, Ceramics, Metallurgy, Geochemistry, Environmental Chemistry, History of and Education in Chemistry.