{"title":"Synthesis of Hexagonal Close-Packed Cobalt Nanoparticles From Thermolysis of Cobalt Carbonyl","authors":"Kyohei Takahashi;Hiroshi Ito;Isao Kanada;Hiroyuki Matsumoto","doi":"10.1109/LMAG.2023.3316608","DOIUrl":null,"url":null,"abstract":"Magnetic materials with low magnetic loss are required to realize both a high-frequency support and a miniaturization of radio frequency components. Hexagonal close-packed cobalt (hcp-Co) nanoparticles are considered suitable for high frequencies due to their nanoparticle morphology and high magnetocrystalline anisotropy. However, the face-centered cubic (fcc) or the ϵ phase with low magnetocrystalline anisotropy is fabricated in the synthetization of Co nanoparticles with a size of less than a few hundred nanometers. In this letter, we investigate the synthesis of Co nanoparticles by the thermolysis of dicobalt octacarbonyl at various temperatures for obtaining Co particles with a single hcp phase. Although Co nanoparticles synthesized at 453 K exhibited a mixture of hcp and fcc phases with an hcp phase ratio of 25%, Co nanoparticles almost achieved the hcp phase ratio of 100% by decreasing the thermolysis temperature to 333 K or lower. Furthermore, we evaluated the permeability spectrum of the composite with Co particles of 10 vol% dispersed in polystyrene. Although the real part of the permeability in the composite containing Co nanoparticles with the mixed phase of fcc and hcp monotonously decreased with frequency, the composite contained Co nanoparticles with a single phase with a suitable constant value up to 3 GHz for high-frequency applications.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2023-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"101","ListUrlMain":"https://ieeexplore.ieee.org/document/10254271/","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Magnetic materials with low magnetic loss are required to realize both a high-frequency support and a miniaturization of radio frequency components. Hexagonal close-packed cobalt (hcp-Co) nanoparticles are considered suitable for high frequencies due to their nanoparticle morphology and high magnetocrystalline anisotropy. However, the face-centered cubic (fcc) or the ϵ phase with low magnetocrystalline anisotropy is fabricated in the synthetization of Co nanoparticles with a size of less than a few hundred nanometers. In this letter, we investigate the synthesis of Co nanoparticles by the thermolysis of dicobalt octacarbonyl at various temperatures for obtaining Co particles with a single hcp phase. Although Co nanoparticles synthesized at 453 K exhibited a mixture of hcp and fcc phases with an hcp phase ratio of 25%, Co nanoparticles almost achieved the hcp phase ratio of 100% by decreasing the thermolysis temperature to 333 K or lower. Furthermore, we evaluated the permeability spectrum of the composite with Co particles of 10 vol% dispersed in polystyrene. Although the real part of the permeability in the composite containing Co nanoparticles with the mixed phase of fcc and hcp monotonously decreased with frequency, the composite contained Co nanoparticles with a single phase with a suitable constant value up to 3 GHz for high-frequency applications.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.