Dual-Metal Atom Electrocatalysts: Theory, Synthesis, Characterization, and Applications

IF 24.4 1区 材料科学 Q1 CHEMISTRY, PHYSICAL
Angus Pedersen, Jesús Barrio, Alain Li, Rhodri Jervis, Dan J. L. Brett, Maria Magdalena Titirici, Ifan E. L. Stephens
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引用次数: 49

Abstract

Electrochemical clean energy conversion and the production of sustainable chemicals are critical in the journey to realizing a truly sustainable society. To progress electrochemical storage and conversion devices to commercialization, improving the electrocatalyst performance and cost are of utmost importance. Research into dual-metal atom catalysts (DACs) is rising in prominence due to the advantages of these sites over single-metal atom catalysts (SACs), such as breaking scaling relationships for the adsorption energy of reaction intermediates and synergistic effects. This review provides an examination of the fundamental theoretical principles and experimental electrochemical performance of DACs in idealized half cells, as well as fuel cells, before proceeding to analyze the methods used for producing and identifying DACs. Current challenges and potential future research directions of DACs are also discussed.

双金属原子电催化剂:理论、合成、表征和应用
电化学清洁能源转换和可持续化学品的生产在实现真正可持续社会的过程中至关重要。提高电催化剂的性能和成本是推动电化学存储和转化装置走向商业化的关键。双金属原子催化剂(dac)的研究越来越受到重视,因为它们比单金属原子催化剂(SACs)具有优势,如打破反应中间体吸附能的标度关系和协同效应。本文综述了理想半电池和燃料电池中DACs的基本理论原理和实验电化学性能,然后分析了生产和鉴定DACs的方法。最后讨论了dac目前面临的挑战和未来可能的研究方向。
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来源期刊
Advanced Energy Materials
Advanced Energy Materials CHEMISTRY, PHYSICAL-ENERGY & FUELS
CiteScore
41.90
自引率
4.00%
发文量
889
审稿时长
1.4 months
期刊介绍: Established in 2011, Advanced Energy Materials is an international, interdisciplinary, English-language journal that focuses on materials used in energy harvesting, conversion, and storage. It is regarded as a top-quality journal alongside Advanced Materials, Advanced Functional Materials, and Small. With a 2022 Impact Factor of 27.8, Advanced Energy Materials is considered a prime source for the best energy-related research. The journal covers a wide range of topics in energy-related research, including organic and inorganic photovoltaics, batteries and supercapacitors, fuel cells, hydrogen generation and storage, thermoelectrics, water splitting and photocatalysis, solar fuels and thermosolar power, magnetocalorics, and piezoelectronics. The readership of Advanced Energy Materials includes materials scientists, chemists, physicists, and engineers in both academia and industry. The journal is indexed in various databases and collections, such as Advanced Technologies & Aerospace Database, FIZ Karlsruhe, INSPEC (IET), Science Citation Index Expanded, Technology Collection, and Web of Science, among others.
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