Catalyst‐ and Light‐free S−H Insertion between Phosphorodithioic Acids and Diazo Compounds: Rapid Access to Dialkylphosphorodithioates

IF 2.7 4区化学 Q1 CHEMISTRY, ORGANIC

Asian Journal of Organic Chemistry Pub Date : 2023-07-01 DOI:10.1002/ajoc.202300053

Meiling Huang , Zi Ye , Dr. Weici Xu , Prof. Dr. Ming‐Hua Xu

引用次数: 0

Abstract

A catalyst‐ and light‐free S−H insertion of phosphorodithioic acids with diazo compounds has been developed, in which phosphorodithioic acid acts not only as an acid promoter but also as a nucleophile. This protocol features fast reaction rate, broad substrate scope, mild conditions, and simple operation, providing a cost‐effective and general approach to diverse phosphorodithioates.

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磷二硫代酸和重氮化合物之间无催化剂和无光S - H插入:快速获取二烷基磷二硫代酸

已经开发了一种无催化剂和无光的二硫代磷酸与重氮化合物的S−H插入，其中二硫代磷酸不仅作为酸促进剂，而且作为亲核试剂。该方案具有反应速率快、底物范围广、条件温和和操作简单的特点，为各种二硫代磷酸酯提供了一种经济有效的通用方法。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Asian Journal of Organic Chemistry CHEMISTRY, ORGANIC-

CiteScore

4.70

自引率

3.70%

发文量

372

期刊介绍： Organic chemistry is the fundamental science that stands at the heart of chemistry, biology, and materials science. Research in these areas is vigorous and truly international, with three major regions making almost equal contributions: America, Europe and Asia. Asia now has its own top international organic chemistry journal—the Asian Journal of Organic Chemistry (AsianJOC) The AsianJOC is designed to be a top-ranked international research journal and publishes primary research as well as critical secondary information from authors across the world. The journal covers organic chemistry in its entirety. Authors and readers come from academia, the chemical industry, and government laboratories.