Solubility of Sb in binary Na2CO3–NaCl molten salt

IF 5.5 1区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING
Yong-ming CHEN , Long-gang YE , Chao-bo TANG , Sheng-hai YANG , Mo-tang TANG , Wen-hai ZHANG
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引用次数: 7

Abstract

The interaction between molten Na2CO3–NaCl salt and Sb and the solubility of Sb in molten salt were investigated in the temperature range of 700–1000 °C. The results show that the dissolution equilibrium of Sb in molten salt can be achieved in 3 h, and the amount of Sb dissolved in the melt decreases as the viscosity decreases. The solubility limits in an eutectic mixture were determined as 5.42%, 2.42%, 0.75% and 0.68% at 700, 800, 900 and 1000 °C, respectively. A high temperature and appropriate content of NaCl will decrease the dissolution of Sb. The insoluble Sb was collected at the bottom of molten salt. The Sb dissolved on the surface of the molten salt is easily oxidized, whereas the Sb dissolved inside the molten salt is randomly distributed in terms of the form of metal Sb.

Sb在二元Na2CO3-NaCl熔盐中的溶解度
在700 ~ 1000℃的温度范围内,研究了熔融Na2CO3-NaCl盐与Sb的相互作用以及Sb在熔盐中的溶解度。结果表明:Sb在熔盐中的溶解在3 h内达到平衡,且Sb在熔盐中的溶解量随着粘度的降低而减少。在700、800、900和1000℃时,共晶混合物中的溶解度极限分别为5.42%、2.42%、0.75%和0.68%。较高的温度和适当的NaCl含量会降低Sb的溶解,不溶性Sb聚集在熔盐底部。溶解在熔盐表面的Sb易被氧化,而溶解在熔盐内部的Sb则以金属Sb的形态随机分布。
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来源期刊
CiteScore
7.40
自引率
17.80%
发文量
8456
审稿时长
3.6 months
期刊介绍: The Transactions of Nonferrous Metals Society of China (Trans. Nonferrous Met. Soc. China), founded in 1991 and sponsored by The Nonferrous Metals Society of China, is published monthly now and mainly contains reports of original research which reflect the new progresses in the field of nonferrous metals science and technology, including mineral processing, extraction metallurgy, metallic materials and heat treatments, metal working, physical metallurgy, powder metallurgy, with the emphasis on fundamental science. It is the unique preeminent publication in English for scientists, engineers, under/post-graduates on the field of nonferrous metals industry. This journal is covered by many famous abstract/index systems and databases such as SCI Expanded, Ei Compendex Plus, INSPEC, CA, METADEX, AJ and JICST.
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