Effect of Zr Content on the Microstructure and Corrosion Resistance of Al–Cu–Mn Alloy

IF 0.6 4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING
Yuping Yang, Ruiming Su, Siyi Ma, Guanglong Li, Yingdong Qu, Rongde Li
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Abstract

In order to improve the overall properties of cast Al–Cu–Mn alloy, the effect of Zr content on the microstructure and corrosion resistance of Al–Cu–Mn alloy was investigated. The microstructures of the alloy were analyzed by scanning electron microscopy and transmission electron microscopy, and the corrosion resistance of the alloy was tested by exfoliation corrosion (EXCO), intergranular corrosion (IGC) and electrochemical corrosion tests. The results show that the corrosion resistance of Al–Cu–Mn alloy with 0.2 wt % Zr is superior to other alloys. Specifically, the EXCO phenomenon of the alloy is lighter, and the rating of EXCO is EA. The IGC depth of the alloy can reach the lower value (56.3 μm). The electrochemical self-corrosion potential (Ecorr), corrosion current (icorr) and corrosion rate (Rcorr) are –0.8046 V, 0.0028 mA m–2 and 0.1558 mm a–1, respectively. The improved corrosion resistance of the Al–Cu–Mn alloy with 0.2 wt % Zr resulted from the formation of the T phase and more uniform dispersive distribution of the Al3Zr phase in the alloy.

Abstract Image

Zr含量对Al-Cu-Mn合金组织及耐蚀性的影响
为了提高铸态Al-Cu-Mn合金的整体性能,研究了Zr含量对铸态Al-Cu-Mn合金组织和耐蚀性的影响。采用扫描电镜和透射电镜对合金的显微组织进行了分析,并通过剥落腐蚀(EXCO)、晶间腐蚀(IGC)和电化学腐蚀试验对合金的耐蚀性进行了测试。结果表明,添加0.2 wt % Zr的Al-Cu-Mn合金的耐蚀性优于其他合金。其中,合金的EXCO现象较轻,EXCO等级为EA,合金的IGC深度可达到较低值(56.3 μm)。电化学自腐蚀电位(Ecorr)、腐蚀电流(icorr)和腐蚀速率(Rcorr)分别为-0.8046 V、0.0028 mA m-2和0.1558 mm a-1。添加0.2 wt % Zr的Al-Cu-Mn合金的耐蚀性提高是由于合金中T相的形成和Al3Zr相的分散分布更加均匀。
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来源期刊
Russian Journal of Non-Ferrous Metals
Russian Journal of Non-Ferrous Metals METALLURGY & METALLURGICAL ENGINEERING-
CiteScore
1.90
自引率
12.50%
发文量
59
审稿时长
3 months
期刊介绍: Russian Journal of Non-Ferrous Metals is a journal the main goal of which is to achieve new knowledge in the following topics: extraction metallurgy, hydro- and pirometallurgy, casting, plastic deformation, metallography and heat treatment, powder metallurgy and composites, self-propagating high-temperature synthesis, surface engineering and advanced protected coatings, environments, and energy capacity in non-ferrous metallurgy.
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