Research Progress on Structural Characteristics, Structure-Application Relationships, and Environmental Application of Biochar-Supported Zero Valent Iron (ZVI-BC)

IF 6.4 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES
Fengmin Li, Xiao Wang, Chunhua Xu
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引用次数: 1

Abstract

Purpose of Review

The biochar-supported zero valent iron (ZVI-BC) can effectively prevent oxidation and agglomeration of ZVI, and improve the utilization rate of ZVI. Recent reviews of ZVI-BC mainly focus on the preparation methods, characterization techniques, and reaction mechanism with pollutants. Since the structural characteristics of biochar have a great impact on Fe0 loading, a comprehensive review of the structural characteristics of biochar is needed to explain its influence on ZVI formation during preparation. And in application of ZVI-BC, the environmental effects on organisms need to be considered. This review of recent research results provides a perspective for understanding the structural characteristics, preparation factors, and ecotoxicity of ZVI-BC.

Recent Findings

The adsorption capacity of ZVI-BC prepared by conventional methods still needs to be improved. The surface-area-normalized reaction rate constant (kSA) of ZVI-BC can be increased to about 180 times by surface modification, adding a stabilizer, element doping, and other modification methods. Recent research on ecotoxicity has shown mostly positive effects of ZVI-BC on microorganisms, animals, and plants during environmental remediation.

Summary

This work reviews the effect of biochar as a support matrix on Fe0 production. The pollutant removal performance is summarized considering the elemental composition, phase components, and surface chemical properties. Also, we discuss the effect of ZVI-BC preparation on contaminant removal and propose methods to optimize the performance of ZVI-BC. The kSA was used to conduct a meta-analysis of kinetic data to illustrate the properties of ZVI-BC. In addition, we evaluate the ecotoxicity of using ZVI-BC in environmental remediation.

Graphical Abstract

Abstract Image

生物炭负载零价铁(ZVI-BC)的结构特性、结构-应用关系及环境应用研究进展
生物炭负载的零价铁(ZVI- bc)能有效防止ZVI的氧化和结块,提高ZVI的利用率。近年来对ZVI-BC的研究进展主要集中在制备方法、表征技术以及与污染物的反应机理等方面。由于生物炭的结构特性对Fe0负载有很大影响,因此需要对生物炭的结构特性进行全面的综述,以解释其在制备过程中对ZVI形成的影响。在ZVI-BC的应用中,需要考虑对生物的环境影响。本文综述了近年来的研究成果,为进一步了解ZVI-BC的结构特征、制备因素和生态毒性提供了一个新的视角。常规方法制备的ZVI-BC吸附性能有待提高。通过表面改性、添加稳定剂、元素掺杂等改性方法,ZVI-BC的表面积归一化反应速率常数(kSA)可提高到180倍左右。最近的生态毒性研究表明,在环境修复过程中,ZVI-BC对微生物、动物和植物的影响主要是积极的。本文综述了生物炭作为载体基质对制备Fe0的影响。从元素组成、相组成和表面化学性质等方面对污染物的去除性能进行了总结。讨论了制备ZVI-BC对污染物去除的影响,并提出了优化ZVI-BC性能的方法。使用kSA对动力学数据进行meta分析,以说明ZVI-BC的特性。此外,我们还对ZVI-BC在环境修复中的生态毒性进行了评价。图形抽象
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来源期刊
Current Pollution Reports
Current Pollution Reports Environmental Science-Water Science and Technology
CiteScore
12.10
自引率
1.40%
发文量
31
期刊介绍: Current Pollution Reports provides in-depth review articles contributed by international experts on the most significant developments in the field of environmental pollution.By presenting clear, insightful, balanced reviews that emphasize recently published papers of major importance, the journal elucidates current and emerging approaches to identification, characterization, treatment, management of pollutants and much more.
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