High-performance multifunctional energy storage-corrugated lattice core sandwich structure via continuous carbon fiber (CCF)/polyamide 6 (PA6) 3D printing

IF 23.2 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES
Hui-Jin Um, Na-Hyun Jeon, Ji-Hwan Shin, Hak-Sung Kim
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Abstract

In this study, an energy storage multifunctional sandwich structure (ESMS) was designed to perform well-balanced and excellent multifunctional performance. The corrugated core sandwich structure was newly developed to prevent the degradation of mechanical properties even when lithium polymer (LiPo) batteries are integrated. The empty space of the corrugated core was used as an energy storage space, and the corrugated core was fabricated via 3D printing technology using a continuous carbon fiber filament. The energy storage characteristics were implemented using LiPo batteries embedded in the neutral axis of the sandwich structure. The static and fatigue bending properties of the ESMSs were analyzed through a three-point bending (3PB) test. A battery charge/discharge test was performed before and after the mechanical tests to analyze the effect of bending loading on the energy storage properties. The conventional foam-core ESMS showed negative changes in flexural properties such as strength (−27% in Foam-SH) and modulus (−22% in Foam-AD) due to the battery embedding. On the other hand, in the case of the 3D-printed core ESMS, no degradation in mechanical properties was observed even though the energy density was 1.7 times higher than that of the foam-core ESMS. Furthermore, no defects or delamination were found in the battery embedded in the 3D-printed core ESMS, unlike the battery embedded in the foam-core ESMS where delamination between the separator, anode, and cathodes occurred after the 3 PB test. Consequently, a 3D-printed core ESMS with superior balanced multifunctional performance can be implemented without degradation of both the mechanical properties and energy storage characteristics.

Abstract Image

连续碳纤维(CCF)/聚酰胺6(PA6)3D打印高性能多功能储能波纹格芯夹芯结构
在本研究中,设计了一种储能多功能夹层结构(ESMS),以实现良好的平衡和优异的多功能性能。波纹芯夹层结构是新开发的,即使在集成锂聚合物(LiPo)电池时也能防止机械性能的退化。将波纹芯的空隙用作储能空间,并使用连续碳纤维丝通过3D打印技术制造波纹芯。使用嵌入夹层结构的中性轴中的LiPo电池来实现能量存储特性。通过三点弯曲(3PB)试验分析了ESMS的静态和疲劳弯曲性能。在机械测试之前和之后进行电池充电/放电测试,以分析弯曲负载对储能性能的影响。由于电池嵌入,传统泡沫芯ESMS的弯曲性能如强度(在泡沫SH中为−27%)和模量(在泡沫AD中为−22%)出现了负面变化。另一方面,在3D打印芯ESMS的情况下,即使能量密度比泡沫芯ESMS高1.7倍,也没有观察到机械性能的退化。此外,与嵌入泡沫芯ESMS中的电池不同,嵌入3D打印芯ESMS的电池中没有发现缺陷或分层,在3 PB测试后,隔板、阳极和阴极之间发生分层。因此,可以在不降低机械性能和储能特性的情况下实现具有优异平衡多功能性能的3D打印芯ESMS。
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来源期刊
CiteScore
26.00
自引率
21.40%
发文量
185
期刊介绍: Advanced Composites and Hybrid Materials is a leading international journal that promotes interdisciplinary collaboration among materials scientists, engineers, chemists, biologists, and physicists working on composites, including nanocomposites. Our aim is to facilitate rapid scientific communication in this field. The journal publishes high-quality research on various aspects of composite materials, including materials design, surface and interface science/engineering, manufacturing, structure control, property design, device fabrication, and other applications. We also welcome simulation and modeling studies that are relevant to composites. Additionally, papers focusing on the relationship between fillers and the matrix are of particular interest. Our scope includes polymer, metal, and ceramic matrices, with a special emphasis on reviews and meta-analyses related to materials selection. We cover a wide range of topics, including transport properties, strategies for controlling interfaces and composition distribution, bottom-up assembly of nanocomposites, highly porous and high-density composites, electronic structure design, materials synergisms, and thermoelectric materials. Advanced Composites and Hybrid Materials follows a rigorous single-blind peer-review process to ensure the quality and integrity of the published work.
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