Mechanical and environmental properties of geopolymer-stabilized domestic waste incineration slag in an asphalt pavement base

Xiaoping Ji , Bo Chen , Xinze Dong , Honglei Lu , Xueyuan Zhang , Shupeng He , Tongda Wu
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Abstract

Domestic waste incineration slag (WIS) includes fly ash and slag. Fly ash is classified as hazardous waste because it contains heavy metals. Most of slag are directly stacked or landfilled due to problems such as large output and low utilization rate. Harmless treatment is imminent. If WIS is used effectively in the road engineering, which can realize the high-quality and high-efficiency recycling of WIS, and it is of great significance to save resources and protect the environment. This study applies a geopolymer prepared from WIS fly ash as a stabilizing agent in WIS blending macadam for use as a pavement base mixture, and reports the mechanical properties (unconfined compressive strength, splitting strength, and resilience modulus) of the geopolymer-stabilized WIS blending macadam (GeoWIS). The leaching concentrations of harmful heavy metals of GeoWIS soaked in water were also investigated. Finally, the strength formation and heavy metal stability mechanisms were explored. The unconfined compressive strength, splitting strength, and compressive resilient modulus of GeoWIS all increased with increasing geopolymer content and decreasing WIS content. The strength of GeoWIS was derived from its geopolymerization and hydration products (C-S-H gel, N-A-S-H gel, and AFt). When the geopolymer content reached 12%–14%, the GeoWIS without natural macadam met the strength criterion of the asphalt pavement base. Through physical adsorption and chemical bonding, the geopolymer significantly reduced the leaching of harmful heavy metals. In GeoWIS with 50% WIS and stabilized with 10% geopolymer, the Cr, Ni, Cd, and Pb concentrations met the grade Ⅲ groundwater standard. Concentrations of heavy metals leached from GeoWIS are low and exert little impact on environment.

地质聚合物稳定生活垃圾焚烧渣在沥青路面基层中的力学和环境性能
生活垃圾焚烧矿渣(WIS)包括粉煤灰和矿渣。粉煤灰因含有重金属而被列为危险废物。由于产量大、利用率低等问题,矿渣大多直接堆放或填埋。无害治疗迫在眉睫。如果将WIS有效地应用于道路工程中,可以实现WIS的高质量、高效率回收利用,对节约资源、保护环境具有重要意义。本研究将以WIS粉煤灰为稳定剂制备的地质聚合物应用于WIS掺合碎石作为路面基层混合料,并报道了地质聚合物稳定的WIS掺混碎石(GeoWIS)的力学性能(无侧限抗压强度、劈裂强度和回弹模量)。并对GeoWIS在水中浸泡后的有害重金属浸出浓度进行了研究。最后,对其强度形成和重金属稳定机理进行了探讨。GeoWIS的无侧限抗压强度、劈裂强度和抗压回弹模量均随地质聚合物含量的增加和WIS含量的降低而增加。GeoWIS的强度来源于其地质聚合和水化产物(C-S-H凝胶、N-A-S-H凝胶和AFt)。当地质聚合物含量达到12%-14%时,不含天然碎石的GeoWIS达到了沥青路面基层的强度标准。通过物理吸附和化学键合,地质聚合物显著降低了有害重金属的浸出率。在含50%WIS并用10%地质聚合物稳定的GeoWIS中,Cr、Ni、Cd和Pb的浓度符合Ⅲ级地下水标准。GeoWIS浸出的重金属浓度较低,对环境影响较小。
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