Effect of the B4C particles on the brazed joints of SiC ceramics and 2219 aluminum alloy

Xianfen Li, Kai Cai, Peng Teng, Peng Hua, Huimin Cheng, Wei Zhou
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Abstract

A two-step process, including the premetallization of the SiC ceramic by Ag-26.7Cu-4Ti+B4C and the followed brazing with the Al-based filler alloy, was developed to join 2219 aluminum alloy and the metallized SiC. The influence of metallization temperature and the B4C addition on the microstructure and mechanical properties of the joint was analyzed. The reaction products of Ti and B4C were detected in the brazing seam, such as Ti2B, TiC and graphite. With increasing of metallization temperature and B4C addition content, the shear strength of joint first increased and then decreased. The joint shear strength reached 14.0 MPa when SiC metallized with Ag-26.7Cu-4Ti+1%B4C at 930°C for 10 min, which showed that appropriate addition of B4C in Ag-26.7Cu-4Ti metallization layer could regulate the coefficient of thermal expansion difference between 2219 aluminum alloy and SiC to relieve the residual stress and improve the shear strength of their brazed joint.

Abstract Image

B4C颗粒对SiC陶瓷与2219铝合金钎焊接头的影响
开发了一种两步工艺,包括用Ag-26.7Cu-4Ti+B4C对SiC陶瓷进行预金属化,然后用铝基填充合金进行钎焊,以连接2219铝合金和金属化的SiC。分析了金属化温度和B4C添加量对接头组织和力学性能的影响。在钎焊焊缝中检测到Ti和B4C的反应产物,如Ti2B、TiC和石墨。随着金属化温度和B4C添加量的增加,接头的抗剪强度先增大后减小。Ag-26.7Cu-4Ti+1%B4C在930°C下对SiC进行金属化处理10min,接头抗剪强度达到14.0MPa,表明在Ag-26.7Cu-4Ti金属化层中适当添加B4C可以调节2219铝合金与SiC之间的热膨胀系数差,以减轻残余应力,提高钎焊接头的抗剪强度。
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