{"title":"Correlation of the Vickers hardness of RO–Al2O3–SiO2 glasses with predicted liquidus temperatures","authors":"Hyojin Lee, William Carty","doi":"10.1111/ijag.16602","DOIUrl":null,"url":null,"abstract":"<p>Vickers hardnesses of RO–Al<sub>2</sub>O<sub>3</sub>–SiO<sub>2</sub> glasses were measured over a broad range of compositions, ranging from ternary endpoints to mixed ratios of RO (CaO with MgO, SrO, or BaO), with the systematic variation of Al<sub>2</sub>O<sub>3</sub> and SiO<sub>2</sub> levels. The hardnesses of CAS and MAS glasses are similar, ranging from 6.7 to 7.2 GPa, with the replacement of CaO with MgO producing a marginal increase in hardness. The substitution of SrO or BaO for CaO generally produced in a decrease in hardness down to 4.5 GPa with BaO. The sensitivity to alumina and silica levels, however, was much greater ranging from a minimum of 4.5 GPa to a maximum of ∼8.2 GPa. The correlation of the Vickers hardness with melting temperature was observed in the CAS system but generally not in the RO-blended glasses. Overall, a combined cation field strength of modifier cations determined the hardness above the critical RO blending ratio.</p>","PeriodicalId":13850,"journal":{"name":"International Journal of Applied Glass Science","volume":"14 2","pages":"268-278"},"PeriodicalIF":2.1000,"publicationDate":"2022-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Applied Glass Science","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1111/ijag.16602","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
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Abstract
Vickers hardnesses of RO–Al2O3–SiO2 glasses were measured over a broad range of compositions, ranging from ternary endpoints to mixed ratios of RO (CaO with MgO, SrO, or BaO), with the systematic variation of Al2O3 and SiO2 levels. The hardnesses of CAS and MAS glasses are similar, ranging from 6.7 to 7.2 GPa, with the replacement of CaO with MgO producing a marginal increase in hardness. The substitution of SrO or BaO for CaO generally produced in a decrease in hardness down to 4.5 GPa with BaO. The sensitivity to alumina and silica levels, however, was much greater ranging from a minimum of 4.5 GPa to a maximum of ∼8.2 GPa. The correlation of the Vickers hardness with melting temperature was observed in the CAS system but generally not in the RO-blended glasses. Overall, a combined cation field strength of modifier cations determined the hardness above the critical RO blending ratio.
期刊介绍：
The International Journal of Applied Glass Science (IJAGS) endeavors to be an indispensable source of information dealing with the application of glass science and engineering across the entire materials spectrum. Through the solicitation, editing, and publishing of cutting-edge peer-reviewed papers, IJAGS will be a highly respected and enduring chronicle of major advances in applied glass science throughout this century. It will be of critical value to the work of scientists, engineers, educators, students, and organizations involved in the research, manufacture and utilization of the material glass. Guided by an International Advisory Board, IJAGS will focus on topical issue themes that broadly encompass the advanced description, application, modeling, manufacture, and experimental investigation of glass.
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