Microstructure and mechanical properties of extruded Mg-6Al-2X (X = Cu/Ni/Fe) alloy used degradable bridge plugs

IF 23.2 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES
Wentao Liu, Baosheng Liu, Shaohua Zhang, Zhiping Lin, Yuezhong Zhang, Pengpeng Wu, Hassan Algadi
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Abstract

Magnesium alloys have recently received much attention as fracturing tools for unconventional oil and gas development. It is well known that increasing micro-galvanic corrosion by doping elements in magnesium alloys is an effective method to get highly degradable alloys. The study aimed to evaluate the effect of different doping elements (i.e., copper, nickel and iron) on the mechanical and degradation behavior of hot extruded magnesium alloys. Nickel-containing alloys show high degradability and mechanical properties compared to the other two alloys. Specifically, the second phase of nickel-containing alloys has a dotted distribution, and this distribution favors the diffusion of corrosion. Meanwhile, the addition of nickel improves the mechanical properties of the alloy with a compressive strength of 430.6 MPa. In addition, based on the first principles and phase diagram simulations. With the addition of nickel, the compounds formed in the alloy act as drivers for the improved degradation properties, resulting in a corrosion rate of 1638.14 mm/year at 93 °C. Therefore, nickel-containing alloys that have been hot extruded show wide application prospects in the field of oil and gas extraction.

Graphical abstract

The influence of Cu/Ni/Fe elements on the microstructure, mechanical properties, and corrosion properties of Mg-6Al (wt. %) alloy was investigated using electrochemical tests, hydrogen evolution, and weight loss measurement.

Abstract Image

可降解桥塞用挤压Mg-6Al-2X (X = Cu/Ni/Fe)合金的组织与力学性能
镁合金作为非常规油气开发中的压裂工具,近年来备受关注。众所周知,在镁合金中掺杂元素增加微电偶腐蚀是获得高降解镁合金的有效方法。本研究旨在评价不同掺杂元素(即铜、镍和铁)对热挤压镁合金力学和降解行为的影响。与其他两种合金相比,含镍合金具有较高的可降解性和力学性能。含镍合金的第二相呈点状分布,有利于腐蚀的扩散。同时,镍的加入提高了合金的力学性能,抗压强度达到430.6 MPa。此外,基于第一性原理和相图进行了仿真。随着镍的加入,合金中形成的化合物成为改善降解性能的驱动因素,在93℃时腐蚀速率为1638.14 mm/年。因此,经热挤压处理的含镍合金在油气开采领域具有广阔的应用前景。摘要采用电化学试验、析氢试验和失重试验研究了Cu/Ni/Fe元素对Mg-6Al (wt. %)合金显微组织、力学性能和腐蚀性能的影响。
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来源期刊
CiteScore
26.00
自引率
21.40%
发文量
185
期刊介绍: Advanced Composites and Hybrid Materials is a leading international journal that promotes interdisciplinary collaboration among materials scientists, engineers, chemists, biologists, and physicists working on composites, including nanocomposites. Our aim is to facilitate rapid scientific communication in this field. The journal publishes high-quality research on various aspects of composite materials, including materials design, surface and interface science/engineering, manufacturing, structure control, property design, device fabrication, and other applications. We also welcome simulation and modeling studies that are relevant to composites. Additionally, papers focusing on the relationship between fillers and the matrix are of particular interest. Our scope includes polymer, metal, and ceramic matrices, with a special emphasis on reviews and meta-analyses related to materials selection. We cover a wide range of topics, including transport properties, strategies for controlling interfaces and composition distribution, bottom-up assembly of nanocomposites, highly porous and high-density composites, electronic structure design, materials synergisms, and thermoelectric materials. Advanced Composites and Hybrid Materials follows a rigorous single-blind peer-review process to ensure the quality and integrity of the published work.
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