B. S. Seplyarskii, R. A. Kochetkov, T. G. Lisina, N. I. Abzalov, D. S. Vasilyev
{"title":"Combustion of 5Ti + 3Si Blends: Impact of Granule Diameter and Ti Particle Size","authors":"B. S. Seplyarskii, R. A. Kochetkov, T. G. Lisina, N. I. Abzalov, D. S. Vasilyev","doi":"10.3103/S106138622202008X","DOIUrl":null,"url":null,"abstract":"<p>This work explains the different ratio of the burning velocities of powder and granulated 5Ti + 3Si mixtures with Ti particles 35 and 120 μm in size due to the influence of impurity gases, which depends on the conditions for heating up the particles ahead of the combustion front. For the first time, the burning velocity inside the granule was obtained using the measured combustion velocities of mixtures of different granule sizes 0.6 ≤ <i>D</i> ≤ 1.7 mm. It turned out to be equal to the velocity of the combustion front in the granulated mixture for fine Ti particles and the velocity of the combustion front in the powder mixture for coarse Ti particles. The difference in the burning rates of the substance of granule and powder mixture serves as a quantitative measure of the influence of impurity gases. The results confirmed the applicability of the developed conditions for heating up the powder components to predict the retarding effect of impurity gases on the synthesis velocity in 5Ti + 3Si powders.</p>","PeriodicalId":595,"journal":{"name":"International Journal of Self-Propagating High-Temperature Synthesis","volume":null,"pages":null},"PeriodicalIF":0.5000,"publicationDate":"2022-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Self-Propagating High-Temperature Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.3103/S106138622202008X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
This work explains the different ratio of the burning velocities of powder and granulated 5Ti + 3Si mixtures with Ti particles 35 and 120 μm in size due to the influence of impurity gases, which depends on the conditions for heating up the particles ahead of the combustion front. For the first time, the burning velocity inside the granule was obtained using the measured combustion velocities of mixtures of different granule sizes 0.6 ≤ D ≤ 1.7 mm. It turned out to be equal to the velocity of the combustion front in the granulated mixture for fine Ti particles and the velocity of the combustion front in the powder mixture for coarse Ti particles. The difference in the burning rates of the substance of granule and powder mixture serves as a quantitative measure of the influence of impurity gases. The results confirmed the applicability of the developed conditions for heating up the powder components to predict the retarding effect of impurity gases on the synthesis velocity in 5Ti + 3Si powders.
期刊介绍:
International Journal of Self-Propagating High-Temperature Synthesis is an international journal covering a wide range of topics concerned with self-propagating high-temperature synthesis (SHS), the process for the production of advanced materials based on solid-state combustion utilizing internally generated chemical energy. Subjects range from the fundamentals of SHS processes, chemistry and technology of SHS products and advanced materials to problems concerned with related fields, such as the kinetics and thermodynamics of high-temperature chemical reactions, combustion theory, macroscopic kinetics of nonisothermic processes, etc. The journal is intended to provide a wide-ranging exchange of research results and a better understanding of developmental and innovative trends in SHS science and applications.