Characteristics of water occurrence in coalbed methane reservoir

Xiaoxiao Sun , Junjie Yi , Jing Li
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引用次数: 1

Abstract

The presence of water, competing with methane for the space, weakens the ability of methane adsorption and diffusion in coal dramatically. The study on the occurrence of water in coal has direct effects on coalbed methane exploitation. In this study, NMR technology was used to obtain water vapor adsorption curves, moreover, the surface adsorption, water cluster formation and pore filling of water in coal pores of coal samples were characterized. Meanwhile, the method based on NMR was first used to quantify the water in different occurrence state in coal pores. The results show that modified BET model can not fit the data in all the pressure history of high rank coal with well-developed micropores and mesopores. Moreover, for pores in high-rank anthracite coal, adsorption water is mainly the indirect adsorption water, and for pores of low-rank bituminous coal, the proportion of direct adsorption water is 50%.

Abstract Image

煤层气储层水赋存特征
水的存在,与甲烷争夺空间,极大地削弱了甲烷在煤中的吸附和扩散能力。研究煤中水分的赋存状态,对煤层气的开采有着直接的影响。本研究利用核磁共振技术获得了水蒸气吸附曲线,并对煤样品的表面吸附、水团簇的形成和水在煤孔隙中的填充进行了表征。同时,首次采用核磁共振方法对煤孔隙中不同赋存状态的水进行了定量。结果表明,改进的BET模型不能拟合微孔和中孔发育的高阶煤的所有压力历史数据。此外,对于高阶无烟煤的孔隙,吸附水主要是间接吸附水,而对于低阶烟煤的孔隙,直接吸附水的比例为50%。
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