Effect of pH, milling time, and Isobam content on porous silicon nitride ceramics prepared by gel casting

Abstract

As a non-toxic copolymer of isobutylene and maleic anhydride, Isobam is successfully used as a dispersant and a gelling agent for fabricating porous Si₃N₄ ceramics by gel casting. The dispersity and rheological properties of the Si₃N₄ slurry are influenced by the pH, milling time, and Isobam content which varies from 0.1 ​wt.% to 0.6 ​wt.%, and these factors are investigated. The slurry with 40 ​vol.% solid content and milled for 4 ​h has a high zeta potential at pH 12 (adjusted by Tetramethyl ammonium hydroxide (TMAH)), which means that the particles are well dispersed. The mechanisms of TMAH are electrostatic repulsion and steric hindrance. The viscosity of the slurry increases with the increase of Isobam content. After pressureless sintering at 1700 ​°C for 2 ​h, a uniform unique interlocking microstructure of rod-like β-Si₃N₄ grains is observed, which may improve the flexural strength of the ceramics by intergranular fracture and particle pullout of β-Si₃N₄ grains. The density and porosity of the samples fluctuate negligibly with the increase of Isobam content, and the Si₃N₄ ceramic with 0.1 ​wt.% Isobam exhibits the highest bending strength of 251.6 ​MPa among all samples.