{"title":"Organocatalytic asymmetric bromohydroxylation of tri-substituted alkenes","authors":"Jing Li, Zhanwei Wang, Xiaoyu Wang, Yian Shi","doi":"10.1016/j.tchem.2023.100039","DOIUrl":null,"url":null,"abstract":"<div><p>This work describes an effective enantioselective bromohydroxylation of <em>tri</em>-substituted alkenes with (DHQD)<sub>2</sub>PHAL as catalyst and H<sub>2</sub>O as nucleophile, providing a variety of corresponding optically active bromohydrins with up to 95% ee.</p></div>","PeriodicalId":74918,"journal":{"name":"Tetrahedron chem","volume":"6 ","pages":"Article 100039"},"PeriodicalIF":0.0000,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Tetrahedron chem","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2666951X23000050","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
This work describes an effective enantioselective bromohydroxylation of tri-substituted alkenes with (DHQD)2PHAL as catalyst and H2O as nucleophile, providing a variety of corresponding optically active bromohydrins with up to 95% ee.
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