Crystallization of Sodium Borosilicate Glass with the Addition of Cr2O3

IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, CERAMICS
M. Yu. Konon, I. G. Polyakova, A. S. Saratovskii, D. P. Danilovich, I. N. Anfimova
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引用次数: 2

Abstract

Glass composition of 6Na2O 22B2O3·70SiO2·2Cr2O3 is studied by scanning electron microscopy, X‑ray powder diffractometry (XRPD), and differential thermal analysis, depending on the duration of heat treatment at a temperature of 550°C. It is established that during heat treatment for 24–96 h, a phase separation structure with interpenetrating phases is formed in the studied glass, and a crystalline phase of eskolaite—Cr2O3 is also formed. With the maximum heat treatment duration of 96 h, cristobalite is formed in the bulk of the glass, which is accompanied by a decrease in the glass transition temperature of the low-viscosity phase. In this case, the intensity of eskolaite peaks decreases. Cr2O3 and SiO2 crystallize apparently due to the substance of the low-viscosity phase.

Abstract Image

Cr2O3对硼硅酸钠玻璃结晶的影响
通过扫描电子显微镜、X射线粉末衍射(XRPD)和差热分析,研究了6Na2O 22B2O3·70SiO2·2Cr2O3的玻璃成分,这取决于在550℃下热处理的持续时间。结果表明,在热处理24 ~ 96 h的过程中,研究玻璃形成了相分离的互穿相结构,并形成了硅石- cr2o3的结晶相。在最大热处理时间为96 h时,玻璃整体形成方石云石,并伴随着低粘度相玻璃化转变温度的降低。在这种情况下,escolaite峰的强度降低。Cr2O3和SiO2由于存在低粘度相而明显结晶。
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来源期刊
Glass Physics and Chemistry
Glass Physics and Chemistry 工程技术-材料科学:硅酸盐
CiteScore
1.20
自引率
14.30%
发文量
46
审稿时长
6-12 weeks
期刊介绍: Glass Physics and Chemistry presents results of research on the inorganic and physical chemistry of glass, ceramics, nanoparticles, nanocomposites, and high-temperature oxides and coatings. The journal welcomes manuscripts from all countries in the English or Russian language.
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