Structural Chemistry of Intermetallides: New Cluster Precursors K46 = 0@Hg6@Pu4Hg36 and K26 = 0@Pu4@Pu4Hg18 for the Crystal Structure of Pu56Hg352-cF408 and K17= Zr@Pu16 for the Crystal Structure of Zr4Pu112-tI116
{"title":"Structural Chemistry of Intermetallides: New Cluster Precursors K46 = 0@Hg6@Pu4Hg36 and K26 = 0@Pu4@Pu4Hg18 for the Crystal Structure of Pu56Hg352-cF408 and K17= Zr@Pu16 for the Crystal Structure of Zr4Pu112-tI116","authors":"V. Ya. Shevchenko, G. D. Ilyushin","doi":"10.1134/S1087659622600624","DOIUrl":null,"url":null,"abstract":"<p>The combinatorial topological analysis and modeling of self-assembly of the Pu<sub>56</sub>Hg<sub>352</sub>-<i>cF</i>408 (<i>a</i> = 21.780 Å, <i>V</i> = 10331.75 Å<sup>3</sup>, space group <i>F</i>-43<i>m</i>) and Zr<sub>4</sub>Pu<sub>112</sub>-<i>tI</i>116 ((<i>a</i> = <i>b</i> = 18.189 Å, <i>c</i> = 7.857 Å, <i>V</i> = 2599.86 Å<sup>3</sup>, space group <i>I</i>4<sub>1</sub>/<i>a</i>) crystal structures are performed by computer methods (the ToposPro software package). The method of complete decomposition of the 3D structure graph into cluster structures was used to determine the framework-forming nanoclusters. For Pu<sub>56</sub>Hg<sub>352</sub>-<i>cF</i>408, 88 variants of decomposition of the 3D structure graph with the number of clusters from 2 to 6 were determined. New two-layer nanoclusters <i>K</i>26 = 0@Pu<sub>4</sub>@Pu<sub>4</sub>Hg<sub>18</sub> and <i>K</i>46 = 0@Hg6@Pu<sub>4</sub>Hg<sub>36</sub> with ‑43<i>m</i> symmetry were found to form a 3D packing. The framework voids contain Hg<sub>4</sub> tetrahedral clusters and Hg spacer atoms. For Zr<sub>4</sub>Pu<sub>112</sub>-<i>tI</i>116, framework-forming nanoclusters <i>K</i>17 = Zr@Pu16 with -4 symmetry are installed. The framework voids contain Pu<sub>4</sub> tetrahedra and Pu spacer atoms.</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":null,"pages":null},"PeriodicalIF":0.8000,"publicationDate":"2023-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Glass Physics and Chemistry","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1134/S1087659622600624","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
引用次数: 0
Abstract
The combinatorial topological analysis and modeling of self-assembly of the Pu56Hg352-cF408 (a = 21.780 Å, V = 10331.75 Å3, space group F-43m) and Zr4Pu112-tI116 ((a = b = 18.189 Å, c = 7.857 Å, V = 2599.86 Å3, space group I41/a) crystal structures are performed by computer methods (the ToposPro software package). The method of complete decomposition of the 3D structure graph into cluster structures was used to determine the framework-forming nanoclusters. For Pu56Hg352-cF408, 88 variants of decomposition of the 3D structure graph with the number of clusters from 2 to 6 were determined. New two-layer nanoclusters K26 = 0@Pu4@Pu4Hg18 and K46 = 0@Hg6@Pu4Hg36 with ‑43m symmetry were found to form a 3D packing. The framework voids contain Hg4 tetrahedral clusters and Hg spacer atoms. For Zr4Pu112-tI116, framework-forming nanoclusters K17 = Zr@Pu16 with -4 symmetry are installed. The framework voids contain Pu4 tetrahedra and Pu spacer atoms.
期刊介绍:
Glass Physics and Chemistry presents results of research on the inorganic and physical chemistry of glass, ceramics, nanoparticles, nanocomposites, and high-temperature oxides and coatings. The journal welcomes manuscripts from all countries in the English or Russian language.